2021
DOI: 10.1002/asia.202100258
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Front Cover: Magnetic Circularly Polarized Luminescence from PtIIOEP and F2‐ppyPtII(acac) under North‐up and South‐up Faraday Geometries (Chem. Asian J. 8/2021)

Abstract: The magnetic circularly polarized luminescence (MCPL) and photoluminescence (PL) spectra of achiral (2,3,7,8,12,13,17,18‐octaethylporphyrinato)platinum(II), PtOEP, and [2‐(4′,6′‐difluorophenyl)pyridinato‐N,C2′]platinum(II) acetylacetonate‐O,O, F2‐ppyPt(acac), in toluene and dichloromethane solutions were recorded under an external magnetic field of 1.6 T with N‐up and S‐up Faraday geometries. The MCPL signs of PtOEP and F2‐ppyPt(acac) were controlled solely by changing the N‐up and S‐up geometries. The MCPL/PL… Show more

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“…Organic and organometallic luminophores are crucial for realizing high‐performance photoluminescence (PL), electroluminescence, optoelectronic, and sensing devices. Recently, optically active substances emitting circularly polarized luminescence (CPL) have been shown to exhibit high tunability of the CPL wavelength, thus making the rational design of organometallic complexes with high Kuhn's dissymmetry ratios ( g CPL ) a challenging task [1–14] . Among the organometallic complexes, optically active lanthanides coordinated with chiral organic ligands exhibit very narrow full‐width at half‐maximum (FWHM) CPL bands for the 4f–4f transitions in the visible and near‐infrared regions [15–24] …”
Section: Introductionmentioning
confidence: 99%
“…Organic and organometallic luminophores are crucial for realizing high‐performance photoluminescence (PL), electroluminescence, optoelectronic, and sensing devices. Recently, optically active substances emitting circularly polarized luminescence (CPL) have been shown to exhibit high tunability of the CPL wavelength, thus making the rational design of organometallic complexes with high Kuhn's dissymmetry ratios ( g CPL ) a challenging task [1–14] . Among the organometallic complexes, optically active lanthanides coordinated with chiral organic ligands exhibit very narrow full‐width at half‐maximum (FWHM) CPL bands for the 4f–4f transitions in the visible and near‐infrared regions [15–24] …”
Section: Introductionmentioning
confidence: 99%