FT-IR and NIR spectroscopic investigation of hydrogen bonding in indole-ether systems

Kordić, Branko; Kovacevic, Marina; Sloboda, Tamara; Vidović, A.; Jović, Branislav

doi:10.1016/j.molstruc.2017.05.035

Cited by 21 publications

(12 citation statements)

References 19 publications

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“…Moreover, the hydroxyl and carboxyl bands in the spectrum of MIL-125-CS-Pb were better defined than those in the spectrum of pure MIL-125-CS, which implied that Pb(II) was embedded through interactions with both the O–H and COO− units [ 24 ]. Reportedly, the stretching and torsional vibrations of these functional groups weaken with the increasing ionic volume, thus resulting in an altered adsorption maximal [ 25 ]. Through the aforementioned analysis, we concluded that Pb(II) reacted chemically with MIL-125-CS and caused changes in the infrared adsorption peaks, thereby demonstrating that Pb(II) was successfully adsorbed onto the surfaces of the MIL-125-CS beads.…”

Section: Resultsmentioning

confidence: 99%

Facile Preparation of Metal-Organic Framework (MIL-125)/Chitosan Beads for Adsorption of Pb(II) from Aqueous Solutions

Liang

Wang

et al. 2018

Molecules

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In this study, novel composite titanium-based metal-organic framework (MOF) beads were synthesized from titanium based metal organic framework MIL-125 and chitosan (CS) and used to remove Pb(II) from wastewater. The MIL-125-CS beads were prepared by combining the titanium-based MIL-125 MOF and chitosan using a template-free solvothermal approach under ambient conditions. The surface and elemental properties of these beads were analyzed using scanning electron microscopy, Fourier transform infrared and X-ray photoelectron spectroscopies, as well as thermal gravimetric analysis. Moreover, a series of experiments designed to determine the influences of factors such as initial Pb(II) concentration, pH, reaction time and adsorption temperature was conducted. Notably, it was found that the adsorption of Pb(II) onto the MIL-125-CS beads reached equilibrium in 180 min to a level of 407.50 mg/g at ambient temperature. In addition, kinetic and equilibrium experiments provided data that were fit to the Langmuir isotherm model and pseudo-second-order kinetics. Furthermore, reusability tests showed that MIL-125-CS retained 85% of its Pb(II)-removal capacity after five reuse cycles. All in all, we believe that the developed MIL-125-CS beads are a promising adsorbent material for the remediation of environmental water polluted by heavy metal ions.

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Section: Resultsmentioning

confidence: 99%

Facile Preparation of Metal-Organic Framework (MIL-125)/Chitosan Beads for Adsorption of Pb(II) from Aqueous Solutions

Liang

Wang

et al. 2018

Molecules

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“…The indole ring is capable of various noncovalent interactions with other molecules by hydrogen bonding through the NH moiety and by π···π stacking, cation···π interactions, etc., through the aromatic moiety [17]. The study of indole inter-and intra-molecular interactions is essential for better understanding of its reactivity and mechanism of interactions in biological systems [18]. The noncovalent and weak interactions with the surrounding groups may also affect the binding properties and redox potential of the metal center in their complexes [19,[20][21][22].…”

Section: Introductionmentioning

confidence: 99%

Molecular self-assembly in indole-based benzamide derivative: Crystal structure, Hirshfeld surfaces and antimicrobial activity

et al. 2017

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Two new compounds, 1H-indole-7-amine (1) and N-(1H-indol-7-yl)-2-methylbenzamide (2)were synthesized and structurally characterized by NMR and FT-IR spectroscopic techniques. The molecular structure of compound 2 was further elucidated by single-crystal X-ray diffraction technique. Moreover, the crystal packing of compound 2 is analyzed in terms of non-covalent N-H···O, C-H···π, and parallel displaced π···π interactions. Hirshfeld surface analysis and decomposed fingerprint plots of the compound 2 were performed to visualize the presence of strong hydrogen bond N-H···O and C-H···π stacking interactions. Hirshfeld surface analysis and decomposed fingerprint plots show that the structure of compound 2 is stabilized by H···H, N-H···O, C-H···π and π···π intermolecular interactions and these interactions contribute mostly to molecular self-assembly in the crystal. In addition, compound 2 was evaluated for both their in-vitro antibacterial and antifungal activity. The obtained results have been reported, explained and compared with fluconazole and ampicillin used as reference drugs. KEYWORDSAntimicrobial activity Single crystal structure Molecular self-assembly Hirshfeld surface analysis Deformation electron density Indole-based benzamide derivative Cite this: Eur.

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“…8, the signal peak of the macromolecule ether bond appeared in the liquefied product with the HZSM-5 catalyst at 1040 cm -1 , but the addition of the catalyst liquefied infrared spectrum did not find the same signal peak. Instead, a small molecular ether bond signal peak appeared at 1061 cm -1 , indicating that the catalyst promoted the degradation of macromolecules (Kordić et al 2017).…”

Section: Ftir Analysis Of Liquefied Product Via Zn/hzsm-5 Catalystsmentioning

confidence: 99%

Preparation of anisole in phenol by Zn/HZSM-5 catalyst from walnut shell catalyzed liquefaction

Liu

Wang

et al. 2021

BioRes

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The promotional effect of Zn was investigated relative to the calcining activation of HZSM-5. It was found that the lignin separated from walnut shell could be liquefied into small molecular ethers such as anisole by the promotional effect of the modified catalyst. Experimental results showed that, after the loading of Zn, the HZSM-5 catalyst retained its original crystal structure, which exhibited good metal dispersion. Besides, due to the existence of two interactions respectively of Zn with Al and Zn with a Brønsted-Lowry acid on the Zn/HZSM-5 catalyst surface, the remaining catalyst intergranular distance increased, particularly for the 2% Zn/HZSM-5 catalyst. The inside of the catalyst was in a state of spherical particle aggregation with a narrow pore size distribution and uniform particle size. The peak intensity of the Si-O stretching vibration was affected by the content of Zn, which was least affected for the 2% Zn/HZSM-5 catalyst. The signal peak of this small molecule ether was not found in the absence of the metal ions, and the catalytic effect of 2% Zn/HZSM-5 was more distinct. Calculated by the mass difference method, the yield of the liquid via the 2% Zn/HZSM-5 catalyst was 59.8%, including phenol and small molecule ethers represented by anisole.

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FT-IR and NIR spectroscopic investigation of hydrogen bonding in indole-ether systems

Cited by 21 publications

References 19 publications

Facile Preparation of Metal-Organic Framework (MIL-125)/Chitosan Beads for Adsorption of Pb(II) from Aqueous Solutions

Facile Preparation of Metal-Organic Framework (MIL-125)/Chitosan Beads for Adsorption of Pb(II) from Aqueous Solutions

Molecular self-assembly in indole-based benzamide derivative: Crystal structure, Hirshfeld surfaces and antimicrobial activity

Preparation of anisole in phenol by Zn/HZSM-5 catalyst from walnut shell catalyzed liquefaction

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