FTIR and UV–VIS optical absorption spectra of gamma-irradiated MoO3-doped lead borate glasses

Redox equilibrium of the UO22+/UO2+ couple in Li2MoO4–Na2MoO4 eutectic melt at 550 °C

“…7 included the absorption band of MoO 2 + . But the absorption band of pentavalent molybdenum species exists at over 25,000 cm À1 in borate glasses [21,22] and the MoO 3 contained in glass has broad absorption bands at 10,000-25,000 cm À1 [23,24]. Therefore, the absorption of molybdenum species does not exist in 5000-9000 cm À1 , and the absorption in 5000-9000 cm À1 is due to UO 2 + .…”

Physical properties and electrochemical performance of molybdenum–lead-germanate glasses and glass ceramics

“…These mixed ionicelectronic conductor glasses have become a current topic mainly in applications such as electrochemical cells, highdensity memories, smart windows, electro-optical and electrochromic devices [11,12]. On the other hand, it is known that the Mo 5 þ ions are a sensitive indicator for the structural changes of the local symmetry in oxide glasses [13].…”

“…It is well known that lead oxide is unique in its influence on the glass structure [14,15] and is widely used in glasses because it enhances the resistance against devitrification, improves the chemical durability and lowers the melting temperature [13]. Despite several detailed investigations, the structure of lead germanate glasses appears to be, as yet, not fully understood.…”

Correlation of structure and ion conduction in La2−xYxMo2O9 (0 ≤ x ≤ 0.2) oxygen ion conductors

“…The band at around 514 cm À1 is due to the symmetric vibration of the Mo-O-Mo linkage. 28 The band centered around 620 cm À1 is assigned to the isolated MoO 6 octahedral unit. 28 The MoO 4 structural group is responsible for the vibrational bands centered at 710 and 790 cm À1 .…”