Functional Characterization of Hydroxy-Polybutadienes

SYNOPSISThe article deals with data treatment problems associated with the estimation (via dualdetection size exclusion chromatography) of the independent distributions of molecular weight and functionality in a derivatized hydroxyl-terminated polybutadiene. Calculations are based on an approach originally developed for linear copolymers and include corrections for ( a ) effect of functional groups on instantaneous mass and molecular weights, ( b ) dependence of refractive index with molecular weight, and (c ) instrumental broadening. Compared to other more laborious analytical methods, the proposed technique is simple and provides accurate results.

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Distributions of functionality and of molecular weights in an hydroxyl‐terminated polybutadiene by dual‐detection size exclusion chromatography

Bielsa

Brandolini

Akcelrud

et al. 1994

J of Applied Polymer Sci

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Functional Characterization of Hydroxy-Polybutadienes

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Distributions of functionality and of molecular weights in an hydroxyl‐terminated polybutadiene by dual‐detection size exclusion chromatography

Distributions of functionality and of molecular weights in an hydroxyl‐terminated polybutadiene by dual‐detection size exclusion chromatography

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