Functional coordination polymers based on redox-active tetrathiafulvalene and its derivatives

Wang, Haiying; Cui, Long; Xie, Jiaze; Leong, Chanel F.; D’Alessandro, Deanna M.; Zuo, Jing‐Lin

doi:10.1016/j.ccr.2016.10.011

Cited by 115 publications

(83 citation statements)

References 90 publications

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“…[62] In view of the unique electronic properties and functional versatility of the TTF electroactiveu nit, its derivatives have been extensively explored as molecular building blocks for constructing electroactiveM OFs and COFs. [63] The main reason for incorporating TTFu nits into frameworks lies in the fact that TTFs can form p-p stacking columns with relativelys hort S•••S interactions, providing efficient charge-transport pathways. Certain TTF-based MOFs and COFs exhibit tunable electrical conductivity andp ermanent porosity and are, thus, amenable to integration into electronic devices.O ther TTF-based porous frameworks have been used in the development of new stimuli-responsivem aterials, based on the relationship between their redox and structural properties.…”

Section: Tetrathiafulvalene(ttf)mentioning

confidence: 99%

Electroactive Organic Building Blocks for the Chemical Design of Functional Porous Frameworks (MOFs and COFs) in Electronics

Souto

Strutyński

Melle‐Franco

et al. 2020

Chemistry A European J

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Electroactive organic molecules have received a lot of attention in the field of electronics because of their fascinating electronic properties, easy functionalization and potential low cost towards their implementation in electronic devices. In recent years, electroactive organic molecules have also emerged as promising building blocks for the design and construction of crystalline porous frameworks such as metal–organic frameworks (MOFs) and covalent‐organic frameworks (COFs) for applications in electronics. Such porous materials present certain additional advantages such as, for example, an immense structural and functional versatility, combination of porosity with multiple electronic properties and the possibility of tuning their physical properties by post‐synthetic modifications. In this Review, we summarize the main electroactive organic building blocks used in the past few years for the design and construction of functional porous materials (MOFs and COFs) for electronics with special emphasis on their electronic structure and function relationships. The different building blocks have been classified based on the electronic nature and main function of the resulting porous frameworks. The design and synthesis of novel electroactive organic molecules is encouraged towards the construction of functional porous frameworks exhibiting new functions and applications in electronics.

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Section: Tetrathiafulvalene(ttf)mentioning

confidence: 99%

Electroactive Organic Building Blocks for the Chemical Design of Functional Porous Frameworks (MOFs and COFs) in Electronics

Souto

Strutyński

Melle‐Franco

et al. 2020

Chemistry A European J

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“…The EPR spectra showed g ¼ 2.002 for I 3 À @2, matching well with those of typical TTFc + cation radicals. 28,[62][63][64] Compound 1 shows redox behavior similar to compound 2 and the generation of the TTFc + radical upon I 2 treatment was conrmed by the EPR study (Fig. S30 †).…”

Section: Probing Redox Activity Of Compounds 1 Andmentioning

confidence: 83%

Zirconium metal–organic frameworks incorporating tetrathiafulvalene linkers: robust and redox-active matrices for in situ confinement of metal nanoparticles

Yuan

Wang

et al. 2020

Chem. Sci.

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“…Coordination polymers are interesting metal-organic hybrid materials in which metal ions or metal-containing clusters act as nodes and organic ligands act as spacers; both units are linked via coordination bonds to form one-, two-or three-dimensional extended structures [1]. This class of compounds has been used as electrodes in supercapacitors [2], gas storage/separation and ion exchange [3][4][5][6][7][8], biological and material science [9,10], sensing [11][12][13][14][15], precursors for the preparation of nano-materials [16], magnetism [17][18][19][20][21], luminescent materials nonlinear optics [22][23][24][25], catalysis [26][27][28][29],.…”

Section: Introductionmentioning

confidence: 99%

The first Fe(II) complex bearing end-to-end dicyanamide as a double bridging ligand: Crystallography study and Hirshfeld surface analysis; completed with a CSD survey

Setifi

Geiger

Jelsch

et al. 2018

Journal of Molecular Structure

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This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain. Treatment of cadmium(II) and zinc(II) with N 2-donor linkages in presence of β-diketone ligand; supported by structural, spectral, theoretical and docking studies

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Functional coordination polymers based on redox-active tetrathiafulvalene and its derivatives

Cited by 115 publications

References 90 publications

Electroactive Organic Building Blocks for the Chemical Design of Functional Porous Frameworks (MOFs and COFs) in Electronics

Electroactive Organic Building Blocks for the Chemical Design of Functional Porous Frameworks (MOFs and COFs) in Electronics

Zirconium metal–organic frameworks incorporating tetrathiafulvalene linkers: robust and redox-active matrices for in situ confinement of metal nanoparticles

The first Fe(II) complex bearing end-to-end dicyanamide as a double bridging ligand: Crystallography study and Hirshfeld surface analysis; completed with a CSD survey

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