Functionalization of lambda-zirconium phosphate with ethylenediaminetetraacetic acid: Synthesis, characterization and applications

Alhendawi, Hussein; Brunet, Ernesto; Juanes, Olga; Idhair, Salem; Hammouda, Huda; Payán, Elena Rodríguez; Rodríguez, María de Victoria

doi:10.1007/s12039-014-0726-5

Cited by 9 publications

(6 citation statements)

References 11 publications

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“…In the starting lambda structure, each zirconium is typically bonded to chloride anion and neutral Phosphoric Acid Industry -Problems and Solutionsdimethylsulphoxide molecule [48,49] which, in principle, can be replaced by any organic chemical structure, that is, carboxylates and amines, in a topotactic manner [32][33][34]45]. Recently, we have prepared several new soft and rigid phosphate-based λ-type organic-inorganic two-dimensional (2D) and 3D frameworks with variable porosity [10,20,32,34].…”

Section: Design Processing and Applications Of Zrp-based Porous Matementioning

confidence: 99%

“…The synthesis and design of materials towards efficiently entrapping Ca 2+ are of great . The results are given in Figure 9 [10]. …”

Section: Metal Uptakementioning

confidence: 99%

“…Phosphate-based-layered organic-inorganic materials, especially those built from octahedral corner-sharing zirconium and tetrahedral phosphate, have attracted much attention and aroused increasing interest from the viewpoint of developing novel functional porous materials for many fields of modern technology, such as luminescence materials [1], chiral molecular selectors [2,3], hydrogen adsorbents [4][5][6], drug-delivery systems [7] and materials for waste water treatment [8][9][10].…”

Section: Introductionmentioning

confidence: 99%

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Phosphate-Based Organic-Inorganic Hybrid Materials: Design, Construction and Technological Applications

Alhendawi¹,

Brunet²,

Payán³

2017

Phosphoric Acid Industry - Problems and Solutions

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The art of designing and synthesizing organic molecules has reached very high levels of sophistication, based on a relatively simple set of rules that guide both the invention and synthesis of new compounds. This set of rules is construed as the rational synthetic method of organic chemistry. As material chemists confronted to the task of building new solid structures with tailored chemical properties, we do inevitably need to develop some rational approach and to establish the corresponding set of rules allowing a realistic level of predictive knowledge in the construction of solid scaffolds. These conditions are reasonably accomplished by the use of layered salts of tetravalent transition metals, namely zirconium phosphate (ZrP). The placing of organic molecules between the layers of ZrP is quite straightforward, can easily be controlled and leads to enduring, solid materials where the confinement makes the organic molecules to show new properties at the supramolecular level. The chemistry of metal phosphates/phosphonates will be detailed in relation with the following topics: (i) molecular recognition, (ii) chemically driven porosity changes, (iii) chiral memory and supramolecular chirality, (iv) luminescence signalling, (v) photo-induced electron-transfer processes, (vi) hydrogen storage, (vii) confinement of drugs and (viii) metal uptake.

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Section: Design Processing and Applications Of Zrp-based Porous Matementioning

confidence: 99%

“…The synthesis and design of materials towards efficiently entrapping Ca 2+ are of great . The results are given in Figure 9 [10]. …”

Section: Metal Uptakementioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Phosphate-Based Organic-Inorganic Hybrid Materials: Design, Construction and Technological Applications

Alhendawi¹,

Brunet²,

Payán³

2017

Phosphoric Acid Industry - Problems and Solutions

Self Cite

View full text Add to dashboard Cite

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“…Therefore, all the attempts to replace the fluoride ligand of the F-phase with other organic or inorganic ones were unsuccessful [11]. On the contrary, several organic and inorganic derivatives have been prepared using the more reactive Cl-phase as precursor [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16].…”

Section: Introductionmentioning

confidence: 99%

“…In this context, there are very few examples in the literature about the synthesis of organic-or inorganic-inorganic materials based on k-ZrP [11][12][13][14][15][16]. Therefore, any contribution to investigate the potential of this substrate can be of interest.…”

Section: Introductionmentioning

confidence: 99%

Lambda-zirconium phosphate covalently pillared with 1,4-biphenyldicarboxylate: a new λ-type rigid microporous framework

Alhendawi

2016

J Incl Phenom Macrocycl Chem

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A new layered pillared material [ZrPO 4 (-OH) 0.60 (C 14 H 8 O 4 ) 0.20 (CH 3 ) 2 SO] based on k-zirconium phosphate (k-ZrP) and 1,4-biphenyldicarboxylic acid (bpdc) has been prepared. The synthesized material is characterized by X-ray diffractometry, FT-IR spectrophotometry, elemental, thermogravimetric and N 2 adsorption/ desorption analyses. The used analysis techniques reveal that the bpdc is successfully incorporated inside the interlayer region of k-ZrP. Regarding the N 2 adsorption/desorption analysis of k-ZrP-bpdc, it gives a moderate specific area of 98 m 2 g -1 and an average pore diameter of 0.88 nm. Therefore, a new k-type rigid microporous framework is obtained. From the practical perspective, there would be a good potential for implementing applications of ZrPO 4 (OH) 0.60 (C 14 H 8 O 4 ) 0.20 (CH 3 ) 2 SO in the fields of inclusion chemistry, molecular shape recognition and heterogeneous catalysis.Graphical abstract A new layered pillared material [ZrPO 4 (OH) 0.60 (C 14 H 8 O 4 ) 0.20 (CH 3 ) 2 SO] based on k-zirconium phosphate (k-ZrP) and 1,4-biphenyldicarboxylic acid (bpdc) has been prepared. The synthesized material is characterized by X-ray diffractometry, FT-IR spectrophotometry, elemental, thermogravimetric and N 2 adsorption/ desorption analyses. The used analysis techniques reveal that the bpdc is successfully incorporated inside the interlayer region of k-ZrP. Regarding the N 2 adsorption/desorption analysis of k-ZrP-bpdc, it gives a moderate specific area of 98 m 2 g -1 and an average pore diameter of 0.88 nm. Therefore, a new k-type rigid microporous framework is obtained. From the practical perspective, there would be a good potential for implementing applications of ZrPO 4 (OH) 0.60 (C 14 H 8 O 4 ) 0.20 (CH 3 ) 2 SO in the fields of inclusion chemistry, molecular shape recognition and heterogeneous catalysis.

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Novel optically active 2D materials based on λ-zirconium phosphate and chiral monocarboxylic acids: Synthesis and characterization

Alhendawi

Brunet

Payán

et al. 2021

J Incl Phenom Macrocycl Chem

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Functionalization of lambda-zirconium phosphate with ethylenediaminetetraacetic acid: Synthesis, characterization and applications

Cited by 9 publications

References 11 publications

Phosphate-Based Organic-Inorganic Hybrid Materials: Design, Construction and Technological Applications

Phosphate-Based Organic-Inorganic Hybrid Materials: Design, Construction and Technological Applications

Lambda-zirconium phosphate covalently pillared with 1,4-biphenyldicarboxylate: a new λ-type rigid microporous framework

Novel optically active 2D materials based on λ-zirconium phosphate and chiral monocarboxylic acids: Synthesis and characterization

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