Functions Containing One Phosphorus and Either Another Phosphorus or As, Sb, Bi, Si, Ge, B, or a Metal

Aitken, R. A.

doi:10.1016/b0-08-044655-8/00078-7

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D P-si Bond Formation1

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2008

2010

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Cited by 2 publications

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“…These two catalysts provide a complementary set of P-Si products and do so in fewer steps than conventional stoichiometric synthesis of silylphosphines [145][146][147]. An alternative route to these molecules, catalytic silylation of a diphosphine, has recently been reported [68].…”

Section: D P-si Bond Formationmentioning

confidence: 97%

Dehydrogenative Bond-Forming Catalysis Involving Phosphines

Waterman¹

2008

COC

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This review presents developments in the young field of dehydrogenative coupling reactions of phosphines. Catalytic phosphorus-element bond formation via dehydrocoupling has rapidly expanded since the first discoveries in the mid 1990s. A survey of the available catalysts, P-P and P-E products, and mechanistic understanding is presented with emphasis on the emerging synthetic applications of this reaction.

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