Phys. Chem. Chem. Phys.
 2023
DOI: 10.1039/d2cp05964a
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Gas phase models of hydride transfer from divalent alkaline earth metals to CO2 and CH2O

Christian Sant Gjermestad
1
,
Mauritz Johan Ryding
2
,
Einar Uggerud
3

Abstract: The reactivity of HMg+, HMgCl, and HMgCl2− in hydride transfer reactions with CO2 and CH2O were studied by means of the reverse reactions—decarboxylation of HCO2MgCln+/0/− and deformylation of CH3OMgCln+/0/− (n...

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