We present transport measurements through an electrostatically defined bilayer graphene double quantum dot in the single electron regime. With the help of a back gate, two split gates and two finger gates we are able to control the number of charge carriers on two gate-defined quantum dot independently between zero and five. The high tunability of the device meets requirements to make such a device a suitable building block for spin-qubits. In the single electron regime, we determine interdot tunnel rates on the order of 2 GHz. Both, the interdot tunnel coupling, as well as the capacitive interdot coupling increase with dot occupation, leading to the transition to a single quantum dot. Finite bias magneto-spectroscopy measurements allow to resolve the excited state spectra of the first electrons in the double quantum dot; being in agreement with spin and valley conserving interdot tunneling processes.Electrostatically defined quantum dots (QDs) offer a compelling platform for spin-qubit-based quantum computation [1]. For that purpose, QDs in semiconductor heterostructures mainly based on GaAs [2, 3] and silicon [4,5] have been studied intensively. For example, high-fidelity single-qubit [6] and two-qubit [7-9] gate operations have been recently demonstrated for silicon qubit devices. Graphene has been early identified as an alternative attractive material platform for spin-qubits thanks to its low nuclear spin densities, weak hyperfine coupling and weak spinorbit interaction promising long spin decoherence times [10]. Physically etched graphene quantum devices including quantum dots [11,12] and double quantum dots (DQDs) [13,14] have been studied for about a decade. Major achievements include the implementation of charge detection [15,16], the observation of spin-states [12] and the measurement of charge relaxation times [17]. However, the influence of disorder, in particular edge disorder [18,19], prevented a precise control of the number of charge carriers on individual QDs making spin-qubit implementation impossible.The advancements in ultra-clean van der Waals heterostructures and in particular the use of local graphite gates allowed for the development of electrostatically defined bilayer graphene (BLG) quantum point contacts [20-23], quantum dots [24-26] and double quantum dots (DQDs) [27,28]. While single-electron and hole occupation has been demonstrated recently for individual QDs [24], the number of charge carriers in DQDs could not be controlled yet [27,28]. The precise control of the number of charge carriers is, however, a requirement for qubit operations in a semiconductor QD device.Here, we show single electron occupation of a bilayer graphene DQD. The electrostatically defined DQD allows for a high tunability of the electrochemical potential such that we can precisely control the number of electrons on * These authors contributed equally to this work. a Corresponding author: luca.banszerus@rwth-aachen.de each of the QDs independently down to zero. The gate voltages tune the interdot tunnel couplin...