Generalized Equation of State for Gases and Liquids

Hirschfelder, Joseph O.; Buehler, Robert J.; McGee, H. A.; Sutton, J. R.

doi:10.1021/ie50579a039

Cited by 73 publications

(34 citation statements)

References 17 publications

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“…Gerry [20], Benedict, Webb, and Rubin [3], Redlich and Kwong [30], Martin and Hou [24], Pings and Sage [18], Hirschfelder, Bueheler, McGee, and Sutton [15], Strobridge [31], Costolnick and Thodos [10], McCarty and Stewart [25], Goodwin [13] and Peng and…”

Section: Martin Classifies the Development Of An Eos Under Two Differmentioning

confidence: 99%

“…A general species EoS that has been widely used in combustion problems is the one originally developed by Hirschfelder et al, [15,16,17] denoted here as HBMS EoS, and introduced next.…”

Section: Single-species Eosmentioning

confidence: 99%

“…A saturation liquid density curve, to serve as the lower boundary for Region III. The Guggenheim/Riedel form is typically employed for this curve [15]:…”

Section: The Hbms Equation Of Statementioning

confidence: 99%

“…A general species EoS that has been widely used in combustion problems is the one originally developed by Hirschfelder et al [15], introduced in section 2.1.1. It also follows the general functional form p = p i (T (v) i ) and its formulation remains the one introduced in section 2.1.1, noting that in the contest of ideal solutions the term red has to be interpreted as red = ( ) i = c i .…”

Section: The Hbms Equation Of State -Ideal Solutionsmentioning

confidence: 99%

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Enhanced Models for Mixtures of Fluids in Chemical Equilibrium at High Pressures

Gaiaschi

2007

39th AIAA Thermophysics Conference

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Section: Martin Classifies the Development Of An Eos Under Two Differmentioning

confidence: 99%

“…A general species EoS that has been widely used in combustion problems is the one originally developed by Hirschfelder et al, [15,16,17] denoted here as HBMS EoS, and introduced next.…”

Section: Single-species Eosmentioning

confidence: 99%

“…A saturation liquid density curve, to serve as the lower boundary for Region III. The Guggenheim/Riedel form is typically employed for this curve [15]:…”

Section: The Hbms Equation Of Statementioning

confidence: 99%

Section: The Hbms Equation Of State -Ideal Solutionsmentioning

confidence: 99%

See 2 more Smart Citations

Enhanced Models for Mixtures of Fluids in Chemical Equilibrium at High Pressures

Gaiaschi

2007

39th AIAA Thermophysics Conference

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“…For each binary system in Table 1 The expressions of fugacity and enthalpy departure are given in the literature (Hirschfelder et al, 1958). For the calculation of fugacity and enthalpy, the H.B.11.S.…”

Section: Determination Of Jciz and V C I~mentioning

confidence: 99%

A generalized correlation for Henry's constants in nonpolar binary systems

Yorizane

Miyano

1978

AIChE Journal

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A generalized correlation for Henry's constant is deveIoped from a threeparameter corresponding states theory for fluid mixtures. Two characteristic parameters are required in each binary system. These parameters are determined for thirty-eight nonpolar binary systems containing quantum gases for solutes. The overall average deviation for calculated Henry's constants is relatively small, about 4 2.5%.

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An equation for the liquid and vapor states of nitrogen

Bukacek

Peck

1961

AIChE Journal

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A great variety of equations of state for gases and liquids has been proposed over the past 75 yrs. Within the past 20 yrs. equations of excellent accuracy over fairly extensive ranges of temperature and density have been proposed for the vapor phase, and in some cases application to vapor-phase mixtures has been demonstrated. To date no single equation of state has been shown to be applicable to both compressed vapor and liquid states. This paper reports the development of an equation which describes the vapor and liquid states of nitrogen in the temperature range to three times the critical temperature and the density range to three times the critical density, including the two-phase boundary. The root mean square error in density prediction over the range specified is 0.7%, and maximum errors in density prediction are less than 1.50/0, except in the vicinity of the critical point. The critical region itself is adequately described, if errors in pressure prediction are used as a criterion.Of the more recent equations of state proposed the work of Benedict, g +EEE€I -I

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Generalized Equation of State for Gases and Liquids

Cited by 73 publications

References 17 publications

Enhanced Models for Mixtures of Fluids in Chemical Equilibrium at High Pressures

Enhanced Models for Mixtures of Fluids in Chemical Equilibrium at High Pressures

A generalized correlation for Henry's constants in nonpolar binary systems

An equation for the liquid and vapor states of nitrogen

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