2009
DOI: 10.1063/1.3116617
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Giant enhancement of top emission from ZnO thin film by nanopatterned Pt

Abstract: The authors report the enhancement of the bandgap emission from ZnO thin films by surface modification and surface plasmon cross-coupling. 12-fold and twofold enhancements of bandgap emission from the metal side of ZnO film were observed by sputtering Pt nanopattern and Pt film onto ZnO film, respectively. Time-resolved photoluminescence indicates that the decay time is slowed down by Pt capping, contrary to common observations. The "abnormal" phenomena are interpreted by considering both the surface modificat… Show more

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Cited by 107 publications
(40 citation statements)
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“…12 In many studies of ZnO/metal structures near-UV emission was enhanced while visible emission was suppressed, because the SPP resonance was close to the bandgap energy of ZnO. [6][7][8] In periodic grating structures, various SPP modes can be excited depending on the periodicity and the properties of the constituent materials. 9 Influences of such multiple SPP-mode excitation on the optical properties of ZnO have not been explicitly investigated.…”
Section: Introductionmentioning
confidence: 98%
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“…12 In many studies of ZnO/metal structures near-UV emission was enhanced while visible emission was suppressed, because the SPP resonance was close to the bandgap energy of ZnO. [6][7][8] In periodic grating structures, various SPP modes can be excited depending on the periodicity and the properties of the constituent materials. 9 Influences of such multiple SPP-mode excitation on the optical properties of ZnO have not been explicitly investigated.…”
Section: Introductionmentioning
confidence: 98%
“…[9][10][11] It has been reported that SPPs at the ZnO/metal interface can enhance the spontaneous electron-hole recombination rate and subsequent photoluminescence (PL) intensity. [5][6][7][8] ZnO thin films usually show broad visible-range PL, originated from defect states, as well as the near band-edge UV emission. 12 In many studies of ZnO/metal structures near-UV emission was enhanced while visible emission was suppressed, because the SPP resonance was close to the bandgap energy of ZnO.…”
Section: Introductionmentioning
confidence: 99%
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“…Such SP-mediated emission has recently been demonstrated in ZnO nanostructures coated by various metals (Ag, Au, Ti, Al and Pt) and dramatic enhancement of the NBE emission was observed [8][9][10][11][12]. It should also be possible to realize the SP-exciton coupling in TM capped ZnO NWs as TMs support SP modes at their surfaces.…”
Section: Introduction Imentioning
confidence: 99%
“…73 Surface defects of ZnO play a major role in determining s R and s NR . In our previous section we have shown the passivation of surface defect with KMnO 4 addition in the precursor solution, therefore we have observed a feeble DLE suggesting higher radiative recombination rate.…”
mentioning
confidence: 99%