Gold and silver complexes with the ferrocenyl-pyrazolate ligand FcCH2pz

Perfluoroarylgold complexes

“…19a), as was shown by DTF calculations [161], and intermolecular aurophilic contacts (see Table 1) that led to association into pairs in [Au(C 6 F 5 )(Fcpy)] [151] (Fig. 19b) and [Au(C 6 F 5 )(FcCH 2 pz)] [152] or into chains in the case of [Au(C 6 F 5 )(FcCH 2 NHpyMe)] [153] (Fig. 19c).…”

“…For the isolation of perfluorophenylgold derivatives ligands with different donor atoms, such as sulfur [Fc(S 2 CNEt 2 ) 2 , Fc(SPh) 2 Tables 1 and 2 [151][152][153][154][155][156][157][158][159][160][161][162][163].…”

Synthesis, physical and antimicrobial studies of ferrocenyl-N-(pyridinylmethylene)anilines and ferrocenyl-N-(pyridinylmethyl)anilines

“…Chem., 2016, 69, 51-66, <http://journals.sabinet.co.za/sajchem/>. reviewed by P. Barbaro et al 43 and A. Fihri et al 44 Potential uses of ferrocenylpyridines Schiff bases includes synthesis of materials for usage in electrochemical sensors, 45 homogenous catalysis, 46 cytotoxic agents, 16 antimicrobial compounds, [47][48][49] antiparasitic, 50 liquid crystals, 51 non-linear optical materials, 52 luminescent systems, 53 as well as coordination of a variety of metal centres to yield novel bimetallic complexes with fascinating architectures, 54,55 organometallic polymers 56 and conducting polymers. 57 In view of the aforementioned potential applications of ferrocenylpyridines and ferrocene derived Schiff bases, we have prepared a series of novel mono-substituted ferrocenyl-N-(pyridinylmethylene)anilines Schiff bases and their corresponding ferrocenyl-N-(pyridinylmethyl)anilines secondary amines.…”

Platinum(II) Alkynyl Complexes Containing N‐ and S‐Propargylated Ligands: Synthesis, Structures and Formation of PtII/AgI Coordination Compounds

“…Complexes 11-16 represent examples of complexes in which an organometallic compound acts as metalloligand. Some examples of such metalloligands include the alkynyl gold(I) macrocycles and [2]catenanes containing pyridyl and bipyridyl backbones that are coordinated to a Pt IV centre, [42] the pyrazolyl-and pyridyl-substituted ferrocenes that are N-coordinated to various Au and Ag species, [43,44] the alkynylfunctionalised bis(pyrazolyl)methane derivatives containing Au/Pd and Pt/Pd [45] and various supramolecular assemblies based on the M-CϵC (4-C 6 H 4 N) (M = Pt, Ru) unit. [40,[46][47][48] …”