Gold carbonyl cations and beyond: homoleptic gold(<scp>i</scp>) complexes with P4 and P4S3 and the half-sandwich cation [Au(C6H6)(CO)]+

Schmitt, Manuel; Nestle, Sarah; Radtke, Valentin; Krossing, Ingo

doi:10.1039/d4cc01374c

Chem. Commun.

2024

DOI: 10.1039/d4cc01374c

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Gold carbonyl cations and beyond: homoleptic gold(i) complexes with P₄ and P₄S₃ and the half-sandwich cation [Au(C₆H₆)(CO)]⁺

Manuel Schmitt,

Sarah Nestle,

Valentin Radtke

et al.

Abstract: Oxidation of Au0 with the synergistic Ag+/0.5 I2 system in the commercial organic solvent 1,2,3,4-tetrafluorobenzene led to the per¬fluoro¬alkoxyaluminate salt of the [Au(CO)2]+ cation known from superacid chemistry. This [Au(CO)2]+...

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Cationic Group 13 and 14 Element Clusters

Barthélemy,

Krossing

2024

Inorg. Chem.

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Anionic and neutral clusters dominate the cluster chemistry of group 13 and 14 elements, many of which have become classic textbook examples of main group element clusters. However, facilitated by the development of unreactive, weakly coordinating anions, the number of known group 13 and 14 cationic cluster compounds has risen rapidly in recent years. Hence, this review aims to give an overview over this research field, which arouses increasing interest owing to the often unusual structures of the cationic clusters, as well as their application in bond activation chemistry. Challenges of the cluster formation are discussed and suitable starting materials are presented, as well as syntheses, structures and the rich follow-up chemistry of (also mixed) group 13 and 14 cluster cations.

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Cationic Group 13 and 14 Element Clusters

Barthélemy,

Krossing

2024

Inorg. Chem.

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Gold carbonyl cations and beyond: homoleptic gold(i) complexes with P₄ and P₄S₃ and the half-sandwich cation [Au(C₆H₆)(CO)]⁺

Abstract: Oxidation of Au0 with the synergistic Ag+/0.5 I2 system in the commercial organic solvent 1,2,3,4-tetrafluorobenzene led to the per¬fluoro¬alkoxyaluminate salt of the [Au(CO)2]+ cation known from superacid chemistry. This [Au(CO)2]+...

Cited by 1 publication

References 42 publications

Cationic Group 13 and 14 Element Clusters

Cationic Group 13 and 14 Element Clusters

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Gold carbonyl cations and beyond: homoleptic gold(i) complexes with P4 and P4S3 and the half-sandwich cation [Au(C6H6)(CO)]+

Abstract: Oxidation of Au0 with the synergistic Ag+/0.5 I2 system in the commercial organic solvent 1,2,3,4-tetrafluorobenzene led to the per¬fluoro¬alkoxyaluminate salt of the [Au(CO)2]+ cation known from superacid chemistry. This [Au(CO)2]+...

Cited by 1 publication

References 42 publications

Cationic Group 13 and 14 Element Clusters

Cationic Group 13 and 14 Element Clusters

Contact Info

Product

Resources

About

Gold carbonyl cations and beyond: homoleptic gold(i) complexes with P₄ and P₄S₃ and the half-sandwich cation [Au(C₆H₆)(CO)]⁺