“…The orientation dependence of graphene on the substrate surfaces, which is vital to the aligned nucleation of graphene islands, is mainly determined by the interaction and the lattice matching degree between graphene and underlying substrates . To date, epitaxial growth of graphene has been reported on the surfaces of Cu(111), Au(111), Pt(111), Ni(111), Ge(110), Ru(0001), Ir(111), Mo(110), Rh(111), In, Sn, and CuNi alloy . Among these, Cu(111) plane is highly advantageous for aligned nucleation and growth of graphene domains as its hexagonal lattice symmetry matches the honeycomb lattice of graphene well (lattice mismatch ≈4%), thereby enabling epitaxial growth of graphene.…”