Graphene oxide linked with N, N′-diamino-1,4,5,8-naphthalenetetracarboxylic bisimide as a stable cathode material for lithium-ion batteries

Song, Yidan; Hu, Yusheng; Sha, Yanyong; Rong, Hongren; Wen, Hao; Liu, Hongjiang; Liu, Qi

doi:10.1007/s11581-019-02868-y

Cited by 12 publications

(9 citation statements)

References 35 publications

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“…The resulting material showed a capacity retention of 85% after 50 cycles in the LIB electrode. 130 Similarly, GO was functionalized with naphthalenediimide diamine (NDIDA) through an amide bond (GO-NDIDA), using a conjugated linker. GO-NDIDA exhibits a capacity retention of 100% after 50 cycles with the aid of a conjugated linker (aniline).…”

Section: Small Redox-active Molecule-functionalized Graphene For Libsmentioning

confidence: 99%

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Covalent functionalization of carbon materials with redox-active organic molecules for energy storage

Khan

Nishina

2021

Nanoscale

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Section: Small Redox-active Molecule-functionalized Graphene For Libsmentioning

confidence: 99%

“…In comparison, the capacity retention of the DNTCB electrode without covalent binding was 16%, after 50 cycles, due to significant dissolution in the electrolyte. 130 Thus, organic molecules covalently grafted onto the surface of CBMs show excellent cycling stability.…”

Section: Covalent Functionalization Of Small Redox-active Molecules On Cbmsmentioning

confidence: 99%

Covalent functionalization of carbon materials with redox-active organic molecules for energy storage

Khan

Nishina

2021

Nanoscale

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“…Recently, various organic materials are studied as cathode materials for LIBs because of merits of evenly distributed elements, tunable structures, and high capacities, such as conductive polymers, [248,249] organic sulfur compounds, [250,251] organic radicals and organic carbonyl compounds. [197,[252][253][254] However, the shortcomings have severely limited their practical Table 6. COF materials for anode and cathode electrodes of LIBs.…”

Section: Cofs As Cathode Materials For Li-ion Batteriesmentioning

confidence: 99%

Progress and Perspective of Metal‐ and Covalent‐Organic Frameworks and their Derivatives for Lithium‐Ion Batteries

Cui

Dong

Chen

et al. 2020

Batteries & Supercaps

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Metal–organic frameworks (MOFs) or covalent–organic frameworks (COFs) have gained increasing attentions due to their high surface area, tunable structure, highly ordered pores and functional composition. Besides their applications in gas adsorption and separation, hydrogen storage, optics, magnetism and drug delivery, they have been widely employed as cathodes, anodes and separators for the research and development in lithium‐ion batteries (LIBs) due to the tunable structure, multi‐electron transfer, short pathway, and robust structural stability, etc. This review summarizes the general applied strategies and cases of MOF, COF and their composites as well as derivatives in LIBs. Compared to inorganic materials, the advantages of MOF/COF materials have made it possible to witness various successful cases with enhanced electrochemical performances. Moreover, this review provides some guidance for the controllable preparation and modification of MOF‐ and COF‐derived nanostructures through molecular engineering, rational design, and doping, as well as functional group modifications. In addition, we highlight timely progresses of the application of organic frameworks in LIBs, and also summarize many strategies of MOF/COF materials and their derivatives on enhancing the energy density, diffusion coefficient, rate performance and cycling stability for next‐generation LIBs with attractive features of high energy density, good rate performance, and superior cyclability.

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“…14 Many methods have been developed for overcoming the dissolution problem, which include constructing carbonsupported organic composites and the polymerization of small molecule carbonyls, etc. 14,15 The construction of coordination polymers (CPs) using the reaction of carbonyl compounds and metal ions with redox activity is a new way. 16 Coordination polymers are a class of compounds composed of metal ions or metal clusters and organic ligands, which include one-dimensional (1D), two-dimensional (2D), and three-dimensional (3D) structures formed by coordination bonding.…”

Section: Introductionmentioning

confidence: 99%

“…Among them, because organic carbonyl compounds have fast kinetics and a high theoretical specific capacity, they receive particular concern, but such materials are easy to dissolve in an electrolyte and have a lower conductivity . Many methods have been developed for overcoming the dissolution problem, which include constructing carbon-supported organic composites and the polymerization of small molecule carbonyls, etc. , The construction of coordination polymers (CPs) using the reaction of carbonyl compounds and metal ions with redox activity is a new way …”

Section: Introductionmentioning

confidence: 99%

A Copper-Based Polycarbonyl Coordination Polymer as a Cathode for Li Ion Batteries

Song

et al. 2021

Crystal Growth & Design

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It is of great significance for the sustainable development of society to search for novel coordination polymer-based electrode materials of lithium ion batteries. Herein, a two-dimensional coordination polymer, )-tetraone; DMF = dimethylformamide), was synthesized and first used as a cathode material of lithium ion batteries. The Cu-CP electrode displayed a better cycling stability and the specific capacity of 40.3 mA h g −1 at 50 mA g −1 after 50 cycles along with a Coulombic efficiency of 96.7%. The electrochemical study for the Cu-CP electrode reveals that both Cu(II) ions and 4-DTBPT ligands may be involved in the electrochemical reaction during charge and discharge. Our work demonstrates again that it is a feasible way to utilize the interaction of metal ions and organic ligands with redox activity for constructing coordination polymers acting as the cathode materials for lithium ion batteries.

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Graphene oxide linked with N, N′-diamino-1,4,5,8-naphthalenetetracarboxylic bisimide as a stable cathode material for lithium-ion batteries

Cited by 12 publications

References 35 publications

Covalent functionalization of carbon materials with redox-active organic molecules for energy storage

Covalent functionalization of carbon materials with redox-active organic molecules for energy storage

Progress and Perspective of Metal‐ and Covalent‐Organic Frameworks and their Derivatives for Lithium‐Ion Batteries

A Copper-Based Polycarbonyl Coordination Polymer as a Cathode for Li Ion Batteries

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