Graphite oxide tribo-layer formation under boundary lubrication of diesel fuel

Abstract

Friction and wear of mechanical components (such as engines) is controlled by some kind of boundary films (also referred to as tribo-layer). In some cases, such boundary film is formed on the contact interface due to a tribo-chemical process in the presence of liquid media. In this paper, we demonstrate the formation of graphite oxide tribo-layer on the contact interface of steel in the presence of diesel fuel liquid media. A Raman spectrometer was used to analyse the tribo-layer structure. Although the intensity is low, it is shown that the tribo-layer has a structure of graphite oxide, demonstrated by the presence of D band peak at approximately 1350 cm−1 and G band peak at approximately 1550 cm−1 in the Raman spectra. Such graphite solid films on the sliding surfaces have ability to control friction and wear. This finding demonstrates the possibility of in-situ formation of solid protective film of a tribo-pair components using the working fluid where the use of lubricants is restricted as they contaminate the working fluid.