The shift towards ecofriendly solvents in perovskite solar cell (PSC) production represents a significant leap towards sustainable renewable energy generation, effectively addressing concerns related to the harmful nature of conventional solvents employed in PSC manufacturing. This review assesses the toxicity of traditional solvents utilized in the PSC fabrication process as well as recent studies and challenges related to substituting toxic solvents with less harmful or green alternatives. Although considerable efforts have been made to adopt greener solvents, this review underscores the variations in evaluations based on specific criteria, highlighting the need for thorough consideration to ensure the viability and sustainability of each solvent replacement. This study offers a comprehensive exploration of the transition to greener solvents in PSC fabrication and elucidates the associated challenges and opportunities in this pivotal shift towards a more environmentally sustainable approach to renewable energy production.This article is protected by copyright. All rights reserved.