2001
DOI: 10.1351/pac200173121895
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Green synthesis via electrolysis in microemulsions

Abstract: Electrolysis in microemulsions is a promising approach for environmentally friendly chemical synthetic methods of the future. Employing microemulsions instead of organic solvents for electrosynthesis has the advantages of lower toxicity and cost, high dissolving power for reactants and mediators of unlike solubility, enhancement of reaction rates by controlling the reduction potentials of mediators, possible reaction pathway control, and recycling of microemulsion components. This paper reviews recent progress… Show more

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Cited by 34 publications
(30 citation statements)
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“…In contrast to dimethylformamide and ionic liquids, bicontinuous microemulsions contain significant amount of water and are indeed much greener media for chemical and electrochemical processes [16]. Rusling et al have reported free radical generation and coupling processes in bicontinuous microemulsion [17][18][19]. Similar electro generated free radical reactions have also been reported [20,21].…”
Section: Introductionmentioning
confidence: 89%
“…In contrast to dimethylformamide and ionic liquids, bicontinuous microemulsions contain significant amount of water and are indeed much greener media for chemical and electrochemical processes [16]. Rusling et al have reported free radical generation and coupling processes in bicontinuous microemulsion [17][18][19]. Similar electro generated free radical reactions have also been reported [20,21].…”
Section: Introductionmentioning
confidence: 89%
“…Rusling and coworkers have investigated some interesting electro organic processes in lEs [13,14]. Inter and intra molecular coupling between activated olefins and alkyl halides have been the main reactions studied extensively [15][16][17].…”
Section: Introductionmentioning
confidence: 99%
“…42,43 Rusling et al conducted pioneering work on the electrochemistry of BME solutions using a glassy carbon (GC) electrode. 44 The electrochemical approach to BMEs shows the dynamic solution structure of BMEs at solid/liquid interfaces.…”
Section: Determination Of Bme Solution Structures At Solid/liquid Intmentioning
confidence: 99%