Grignard metathesis (GRIM) polymerization for the synthesis of conjugated block copolymers containing regioregular poly(3-hexylthiophene)

Stefan, Mihaela C.; Bhatt, Mahesh P.; Sista, Prakash; Magurudeniya, Harsha D.

doi:10.1039/c1py00453k

Cited by 115 publications

(79 citation statements)

References 63 publications

(104 reference statements)

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“…[62] The process is also given substantial coverage in most recent reviews that, in part, relate to polymer synthesis, living or controlled polymerization or novel architectures. Some of those that include significant mention of RAFT polymerization include reviews on RDRP, [63] mechanism and reagent design, [11,64,65] click chemistry, [66][67][68][69][70][71][72] synthesis of telechelics, [73] the polymerization of carbazole-containing monomers, [74] N-vinyl-1,2,3-triazoles, [75] N-vinyl heterocycles, [76] fluoro-monomers, [77] and glycomonomers, [78][79][80] synthesis of metallopolymers, [81] conjugated block copolymers, [82] dye-functionalized polymers, [83] stimuliresponsive polymers, [84,85] complex architectures, [86,87] polyolefin blocks, [88] biopolymer-polymer conjugates and bioapplications, [59,[89][90][91][92][93] polysaccharide modification, [94,95] polymerization in heterogeneous media, [96,97] microwave-assisted polymerization, [65,98,99] industrial prospects for RDRP, [100,…”

Section: Introductionmentioning

confidence: 99%

Living Radical Polymerization by the RAFT Process – A Third Update

2012

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This paper provides a third update to the review of reversible deactivation radical polymerization (RDRP) achieved with thiocarbonylthio compounds (ZC(¼S)SR) by a mechanism of reversible addition-fragmentation chain transfer ( Chem. 2009Chem. , 62, 1402. This review cites over 700 publications that appeared during the period mid 2009 to early 2012 covering various aspects of RAFT polymerization which include reagent synthesis and properties, kinetics and mechanism of polymerization, novel polymer syntheses, and a diverse range of applications. This period has witnessed further significant developments, particularly in the areas of novel RAFT agents, techniques for end-group transformation, the production of micro/nanoparticles and modified surfaces, and biopolymer conjugates both for therapeutic and diagnostic applications.

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Section: Introductionmentioning

confidence: 99%

Living Radical Polymerization by the RAFT Process – A Third Update

2012

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“…There are additionally many more reviews which deal more general with RDRP but which, nonetheless, have a substantial section on RAFT polymerization. Some of those that include significant mention of RAFT polymerization include general reviews on RDRP (102), RDRP mechanisms and reagent design (103,104), click chemistry (105-109), photo-initiated RDRP (110) synthesis of telechelics (111), polymerization of carbazole-containing monomers (112), N-vinyl-1,2,3-triazoles (113), N-vinyl heterocycles (114), glycomonomers (115,116), synthesis of metallopolymers (117), conjugated block copolymers (118), dye-functionalized polymers (119), stimuli responsive polymers (120)(121)(122), complex architectures (123), biopolymer-polymer conjugates and bioapplications (97,(124)(125)(126)(127)(128)(129), polysaccharide modification (130), polymerization in heterogeneous media (131), microwave-assisted polymerization (132,133) and industrial prospects for RDRP (134).…”

Section: Recent (2011-2014) Applications Of Raft Polymerization At Csiromentioning

confidence: 99%

RAFT Polymerization – Then and Now

Moad

2015

ACS Symposium Series

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RAFT Polymerization is currently one of the most versatile and most used methods for implementing reversible deactivation radical polymerization (RDRP) otherwise known as controlled or living radical polymerization. This paper will briefly trace the historical development of RAFT with reference to the kinetics and mechanism of the process. It will also highlight the most recent developments in our laboratories at CSIRO during the period 2011-2014 specifically covering such areas as kinetics and mechanism, RAFT agent development, end-group transformation, RAFT crosslinking polymerization, monomer sequence control and multi-block copolymer synthesis, and high throughput RAFT polymerization.

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“…15). This synthetic method, now known as catalyst transfer polycondensation (CTP) (13)(14)(15)(16)(17)(18)(19), paved the way for synthesizing all-conjugated diblock copolymers (20)(21)(22)(23)(24)(25)(26)(27), star polymers (28,29) and surface-grafted polymers (30)(31)(32). CTP also provides access to all-conjugated gradient sequence copolymers (33)(34)(35)(36).…”

Section: Introductionmentioning

confidence: 99%