2020
DOI: 10.1002/adma.202004192
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Guest Encapsulation within Surface‐Adsorbed Self‐Assembled Cages

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Cited by 15 publications
(10 citation statements)
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References 57 publications
(111 reference statements)
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“…As proof-of-principle, the group demonstrated the separation of Diels−Alder reagents by two immobilized cages. 220 In summary, the immobilization of coordination cages on various heterogeneous support materials has been reported. Raymond and Nitschke have demonstrated the ability of immobilized cages to act as catalysts under continuous flow conditions, in the case of Raymond even with higher performance than the homogeneous analogues.…”
Section: Toward Implementation In Devicesmentioning
confidence: 97%
See 1 more Smart Citation
“…As proof-of-principle, the group demonstrated the separation of Diels−Alder reagents by two immobilized cages. 220 In summary, the immobilization of coordination cages on various heterogeneous support materials has been reported. Raymond and Nitschke have demonstrated the ability of immobilized cages to act as catalysts under continuous flow conditions, in the case of Raymond even with higher performance than the homogeneous analogues.…”
Section: Toward Implementation In Devicesmentioning
confidence: 97%
“…In recent literature, several methods have been developed to immobilize coordination cages on different heterogeneous supports such as gold, , alumina, and polymers . Depending on the purpose and the nature of the support, different strategies are used as depicted in Figure .…”
Section: Toward Implementation In Devicesmentioning
confidence: 99%
“…Surface adsorption can also be used to fragment complex materials. In 2021, Nitschke and co‐workers immobilized MOCs on alumina based on electrostatic interactions; anionic MOC‐32 adsorbs onto an acidic support with a positively charged surface, whereas cationic MOC‐33 adsorbs onto a basic support with negative charges [80] . As showed in Figure 22, the MOC‐32‐acidic alumina hybrid composite ( 60 ) bound cyclopentadiene in water, while the MOC‐32‐basic alumina hybrid composite ( 61 ) bound N ‐propyl maleimide in water.…”
Section: Incorporation Of Mocs Into Other Matricesmentioning
confidence: 99%
“…1–6 Both the size and the functional site of spaces are, needless to say, key factors for the selective encapsulation of specific target molecules. 7–11 Such confined spaces with desirable functional environments have been applied as key platforms for reversible adsorption/desorption processes in various fields including purification, separation, recognition, decontamination, guest binding, intra-porous dynamics, delivery, storage, transport, extraction, catalysis, and proton conductivity. 12–33 In particular, the structure of water clusters within such confined volumes is dominated not by the van der Waals interactions but instead by directional hydrogen bonding.…”
Section: Introductionmentioning
confidence: 99%