Guest Partitioning and High CO2 Selectivity in Hydroquinone Clathrates Formed from Ternary (CO + CO2 + H2) Gas Mixtures

Abstract

Clathrate formation and guest behaviors in hydroquinone (HQ) clathrates were investigated for the first time using ternary (CO + CO2 + H2) gas mixtures. Two gas compositions (low and high CO2 concentrations) were used to simulate synthesis gases generated from various sources. After reaction at 2.0, 4.0, and 6.0 MPa, the conversion yield of pure HQ to the clathrate form reached >90% if the CO2 partial pressure was 0.7 MPa or higher. In addition, CO2 was the most abundant occupant, whereas CO was only detectable at higher CO concentrations and experimental pressures. The separation efficiency values expressed as molar ratios of CO2 to CO in the solid clathrate form were found to be 12.7 and 23.9 MPa at 4.0 and 6.0 MPa, respectively. The experimental and the calculated results in this study provide information useful for the design of a clathrate-based separation process for synthesis gases from various sources (i.e., synthesis gases with various compositions).