Helicene Covalent Organic Frameworks for Robust Light Harvesting and Efficient Energy Transfers
Cong Yin,
Xingyao Ye,
Shanshan Tao
et al.
Abstract:Helicenes represent a class of fascinating π compounds with fused yet folded backbones. Despite their broad structural diversity, harnessing helicenes to develop well‐defined materials is still a formidable challenge. Here we report the synthesis of crystalline porous helicene materials by exploring helicenes to synthesize covalent 2D lattices and layered π frameworks. Topology‐directed polymerization of [6]helicenes and porphyrin creates 2D covalent networks with alternate helicene‐porphyrin alignment along t… Show more
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