High-efficiency green catalytic conversion for waste CS₂ by non-noble metal cage-based MOFs: an access pathway to high-value thiazolidine-2-thione

Abstract

Green and effective disposal of Carbon disulfide (CS2) waste into high-valued chemicals under mild conditions is meaningful and challenging. Herein, a novel 3D cluster-based metal-organic framework (MOF) {(Me2NH2)2[Co3(µ3-O)(XN)(BDC)3]∙4DMF∙5MeOH}n (compound 1)...