High Molecular Weight Polymers from Propylene and 1-Butene

Fontana, C. M.; Herold, R. J.; Kinney, Erin; Miller, R. C.

doi:10.1021/ie50516a050

Cited by 16 publications

(5 citation statements)

References 4 publications

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“…The case of PB1 is clearly different and we think that eq 8 is not mainly responsible for the formation of unit F. More likely is a 1,3-hydride shift which would generate an isobutyl group, eq 9 since the migrating tendency of the hydride ion is more favored them that of the methide ion.1 However, the signal of unit G is expected in a region of the 13C-NMR spectrum (22)(23) ppm) which contains other signals, and thus no experimental evidence can be obtained.…”

Section: Resultsmentioning

confidence: 82%

On the Cationic Polymerization of Olefins and the Structure of the Product Polymers. 2. Poly-1-butene

Corno¹,

Ferraris²,

Priola³

et al. 1979

Macromolecules

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Section: Resultsmentioning

confidence: 82%

On the Cationic Polymerization of Olefins and the Structure of the Product Polymers. 2. Poly-1-butene

Corno¹,

Ferraris²,

Priola³

et al. 1979

Macromolecules

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“…the temperature rose from -78 t.o +I 0°C. The polymerization was practically over in [4][5] min. as evidenced by a steady and rapid decrease of the temperature.…”

Section: Methodsmentioning

confidence: 99%

Infrared spectrum of cationically produced polypropylene

Immergut¹,

Kollmanan²,

Malatesta³

1961

J. Polym. Sci.

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“…These materials are used in the production of alkyl-aryl sulfonate detergents and motor oil additives (90,91).…”

Section: Chemical Propylene Oligomers Through Acid-catalyzed Frie-mentioning

confidence: 99%

Propylene

Calamur¹,

Carrera²,

Staff³

2005

Kirk-Othmer Encyclopedia of Chemical Technology

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Propylene is an important industrial chemical used as a feedstock in the production of polypropylene, acrylonitrile, propylene oxide, 2‐propanol, alkylated fuels, and other chemicals. It is obtained from steam cracking in pyrolysis furnaces in olefins plants and in refinery catalytic‐cracking reactors. Distillation in multitray columns yields purities in excess of 99.5 wt%. The physical and chemical properties of propylene are well characterized. Under ambient conditions, it is a colorless gas and has anesthetic properties at high concentrations. Propylene is usually transported in the liquid state at high pressures. Proper precautions must be taken when handling propylene.

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High Molecular Weight Polymers from Propylene and 1-Butene

Cited by 16 publications

References 4 publications

On the Cationic Polymerization of Olefins and the Structure of the Product Polymers. 2. Poly-1-butene

On the Cationic Polymerization of Olefins and the Structure of the Product Polymers. 2. Poly-1-butene

Infrared spectrum of cationically produced polypropylene

Propylene

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