We report on high-precision QEC values of the 21 Na→ 21 Ne and 23 Mg→ 23 Na mirror β-transitions from mass measurements with ISOLTRAP at ISOLDE/CERN. A precision of δm/m = 9 · 10 −10 and δm/m = 1.5 · 10 −9 was reached for the masses of 21 Na and 23 Mg, respectively. We reduce the uncertainty of the QEC values by a factor five, making them the most precise experimental input data for the calculation of the corrected Ft-value of these mixed Fermi/Gamow-Teller transitions. For the 21 Na→ 21 Ne QEC value, a 2.3σ deviation from the literature QEC-value was found.