High pressure and high temperature phase transformations of covalent triazine-based frameworks

In this work, full triazine two-dimensional frameworks (2DC 3 N 3 ) were synthesized and used to detect metal ions in aqueous solutions. 2DC 3 N 3 showed excellent performance to sense Hg(II) with high selectivity (>96%) and was designed as a recyclable sensor for Hg(II) detection. 2DC 3 N 3 was synthesized using catalyst-free [2+2+2] cyclotrimerization of sodium cyanide and cyanuric chloride at ambient conditions. The as-prepared 2DC 3 N 3 sheets with several hundred micrometers lateral size exhibited strong excitation-dependent fluorescence with 63% quantum yield and maximum emission at 428 nm. The emission of 2DC 3 N 3 decreased with 14.74 × 10 3 L•mol −1 quenching constant (K SV ) upon interaction with Hg 2+ ions. This effect was used as a strong signal to detect Hg(II) with a 0.98 nM detection limit. The high Hg 2+ removal capacity of 2DC 3 N 3 was attributed to cooperative interactions of nitrogen atoms of 2DC 3 N 3 pores and Hg 2+ , as suggested by computational studies. Taking advantage of the straightforward synthesis of 2DC 3 N 3 and its selectivity, it can be used as an efficient platform for monitoring Hg 2+ in waste and drinking water.

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High pressure and high temperature phase transformations of covalent triazine-based frameworks

Cited by 3 publications

References 50 publications

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