High rate capability and thermal stability of monoclinic-Li2MnSiO4 – A promising high capacity cathode material for lithium batteries

A critical review on orthosilicate Li2MSiO4 (M = Fe, Mn) electrode materials for Li ion batteries

“…EIS results obtained at open circuit voltage showed LFS/sucrose-600 delivered lowest R ct of 43.1 Ω with lithium-ion diffusion coefficient D Li + of 2.53 × 10 −16 cm 2 s −1 . To improve the poor conductivity of Li 2 MnSiO 4 Shree Kesavan and Michael [173] synthesized pristine monoclinic LMS coated with sucrose as carbon source. The electronic conductivity of LMS sample was improved by decreasing contact resistance in between particles with the help of wire like structure.…”

Aqueous synthesis of Li2MnAO4/C (A = Si, Ge) as positive electrode active materials for lithium-ion batteries by acid–base reaction

“…[10][11][12][13] Furthermore, these materials have poor electron conductivities, because of which carbon coating or compositing is required as an additional process. [14][15][16][17] Therefore, effective methods of synthesizing and improving conductivity are desired. In negative electrode materials research, a-Fe 2 O 3 and Ni 0.5 Co 0.5 Fe 2 O 4 were synthesized by an environmentally and economically friendly method that used water solvent at ordinary pressure.…”