High resolution study of the M₄₅N₆₇N₆₇and M₄₅N₄₅N₆₇Auger transitions in the 5d series

Pt/Co‐Au Dumbbell‐Like Nanorods for Enhanced Electrocatalytic Performance of Formic Acid Electrooxidation

“…The first one at 70.9 and 74.1 eV could be attributed to 4f7/2 and 4f 5/2 of Pt(0). Compared with the reported data on metallic Pt, these peaks slightly move to the low binding energies. The other doublet at 71.6 and 74.9 eV probably comes from Pt(II) species adsorbed on the surface.…”

Ordered NiO-TiO2 nanotube arrays as an efficient catalyst support for methanol oxidation

“…2d, Ni 2p 1/2 and Ni 2p 3/2 peaks were, respectively, found at 871.4, 861.5, and 854.2 eV, which are the standard Ni 2þ peaks in NiO [20]. In addition, Pt4f 7/2 and Pt4f 5/2 peaks are found at binding energies of 71.4 and 74.6 eV, respectively, which are fairly close to the standard Pt4f 7/2 and Pt4f 5/2 band energies of Pt 3 Ti [21,22]. On the basis of the XRD and XPS results, we deduced that catalyst (Pt)Àsupport (TiO 2 , NiTi and Ni 3 Ti) interactions were formed between Pt particles and the support.…”

High performance and durable nanostructured TiN supported Pt50–Ru50 anode catalyst for direct methanol fuel cell (DMFC)

“…The Pt 4f doublet peaks for the JM-Pt(Ru), observed at 70.9 eV and~74.5 eV (see Fig. S3 in the supporting information), correspond to Pt 4f 7/2 and Pt 4f 5/2 binding energy, respectively, corresponding to the elemental oxidation state of zero for the metal [34,35]. Correspondingly, Pt 4f 7/2 and Pt 4f 5/2 peaks for the CSGPt(Ru)/TiN catalyst are however shifted to higher binding energy in comparison to JM-Pt(Ru) catalyst.…”