“…Since the separation between the main peak and satellite is --~13 eV for Fe complexes, a detector with 10 3 energy resolution would be sufficient for measuring spin-polarized spectra. The development of ultra-high-energy-resolution detectors, such as the bolometer (Le Gros et al, 1995) and the superconducting tunnel junction detector (Frank et al, 1996), may eventually eliminate the whole crystal spectrometer for spin-polarized studies. It is, however, essential to have spectrometer resolution which is better than l eV in order to utilize the chemical shifts (,-~1 eV) in mixed-valence and mixed-spin-state clusters for siteselective XAS.…”