High Temperature Ionic Liquids: Thermal Properties and Dimorphism in [1-(Methoxycarbonyl) Ethyl] Triphenylphosphonium p-Toluenesulfonate

Kariuki, Benson M.; Bonnet, Ludovic G.; Warren, John E.

doi:10.1007/s10870-009-9549-5

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2011

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“…For a related synthetic strategy, see: Ganesan & Alias (2008). For salts containing the triphenylphosphonium cation, see: Kariuki et al (2009). For applications of phosphonium salts as ionic liquids, see: Cieniecka-Roslonkiewicz et al (2005).…”

Section: Related Literaturementioning

confidence: 99%

[1,4-Phenylenebis(methylene)]bis(triphenylphosphonium) bis(tetrafluoroborate)

Ibrahim¹,

Koorbanally²,

Ramjugernath³

et al. 2011

Acta Cryst E

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The crystal structure of the title salt, C44H38P2 2+2BF4 −, consists of discrete dications interlaced with the BF4 − counter-ions. In each cation, both phosphonium groups lie on the same side of the plane of the central benzene ring. The tetrafluoroborate anions are involved in intensive thermal motion, thus some B—F bond lengths [range 1.329 (6) to 1.391 (6) Å] deviate significantly from their standard values.

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Section: Related Literaturementioning

confidence: 99%