2021
DOI: 10.26434/chemrxiv-2021-zcdzn
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Highly Selective Anion Recognition, Extraction and Deep Removal Using a Superphane

Abstract: Highly selective anion recognition and extraction are critical and challenging to deep removal of pollutants from the environment and effective recovery of valuable chemicals from low–content (at sub–ppm or ppb level) sources. Herein, we detail the gram–scale synthesis of a superphane 2, a new supramolecular host that was found capable of encapsulating ReO4– with high selectivity, as suggested by the single–crystal structures, NMR spectroscopy and theoretical calculations. Under solid–liquid extraction condidt… Show more

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