2024
DOI: 10.1002/chem.202403248
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Host‐Guest Interactions Facilitated by Chalcogen Bonding within Selenadiazole Functionalised Porphyrin Nanotubes

Catriona Thomson,
Marc‐Antoine Sani,
Keith F. White
et al.

Abstract: The structural rigidity of tetrakis(4‐pyridyl)porphyrin (TPyP) has been utilised to prepare a robust novel porous coordination polymer of composition Cd2(TPyP)(sez)2 (TPyP = 5,10,15,20‐tetra(4‐pyridyl)porphyrin, sez = 1,2,5‐benzoselenadiazole‐5‐carboxylate). The coordination polymer may be described as a hexagonal porphyrin nanotube (PNT) and has the potential to bind guest molecules through chalcogen bonding. Single crystal X‐ray diffraction (SCXRD) data indicate an internal pore diameter ~9 Å which represent… Show more

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