How hydrothermal synthesis improves the synthesis of (Zr,Ce)SiO4 solid solutions
Thomas Barral,
Paul Estevenon,
Yann Chanteau
et al.
Abstract:Although ZrSiO4 is the most well-known compound in the zircon-structured family (space group I41/amd), the experimental conditions for preparing pure and well-crystallized phases which are doped with tetravalent element via...
“…26) aligning well with the experimental phase transition pressure observed at around 15 GPa. 25 However, there is less research on CeSiO 4 stetindite, on the theoretical side, 27,28 with only one study present in the literature. 29 To date, there is also only one experimental study of CeSiO 4 under high pressure.…”
Density functional theory plus Hubbard U (DFT+U) methodology was used to calculate the structures and energetic landscapes of CeSiO4, including its stetindite and scheelite phases from ambient pressure to ~24...
“…26) aligning well with the experimental phase transition pressure observed at around 15 GPa. 25 However, there is less research on CeSiO 4 stetindite, on the theoretical side, 27,28 with only one study present in the literature. 29 To date, there is also only one experimental study of CeSiO 4 under high pressure.…”
Density functional theory plus Hubbard U (DFT+U) methodology was used to calculate the structures and energetic landscapes of CeSiO4, including its stetindite and scheelite phases from ambient pressure to ~24...
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