Hybrid aqueous battery based on Na3V2(PO4)3/C cathode and zinc anode for potential large-scale energy storage

Li, Guolong; Yang, Ze; Jiang, Yan; Zhang, Wuxing; Huang, Yunhui

doi:10.1016/j.jpowsour.2016.01.058

Cited by 159 publications

(134 citation statements)

References 49 publications

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“…[3][4][5] Hence, many aqueous batteries, especially alkaline batteries, utilize zinc metal as the anode. [6][7][8][9][10][11][12][13][14][15] Even though there are many advantages of using zinc metal as the anode in aqueous batteries, secondary zinc batteries have not been widely commercialized duet os everal limitations, mainly from the zinc electrode. The major problemsn eed to be solved are metal corrosion,d endrite formation, and hydrogen evolution.…”

Section: Introductionmentioning

confidence: 99%

Highly Sustainable Zinc Anodes for a Rechargeable Hybrid Aqueous Battery

Sun

Hoang

et al. 2017

Chemistry A European J

145

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The synthesis of novel zinc electrodes has been successfully implemented by using the electroplating method with the aid of inorganic additives in the electroplating solution. The selected inorganic additives are indium sulfate, tin oxide, and boric acid. From X-ray diffraction results, these synthesized zinc electrodes prefer (002) and/or (103) crystallographic orientations, representing basal morphology and high resistance to dendrite growth. The corrosion rates of these electroplated zinc samples decrease as much as 11 times smaller than the corrosion rate on zinc foil when the zinc materials are in contact with the aqueous electrolyte of a rechargeable hybrid aqueous battery (ReHAB). The ReHABs employing these anodes exhibit up to a threefold decrease in float charge current density after a seven-day constant-voltage charging at 2.1 V versus Zn /Zn. Furthermore, the capacity retention is up to 15 % higher than the performance of battery containing commercial Zn after 1000 cycles of charge-discharge. The significant advancements are attributed to the careful preparation of the anode, which contains appropriate crystallographic orientation and morphology.

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Section: Introductionmentioning

confidence: 99%

Highly Sustainable Zinc Anodes for a Rechargeable Hybrid Aqueous Battery

Sun

Hoang

et al. 2017

Chemistry A European J

145

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“…[14,15] Furthermore,c ompared with aqueous electrolytes,the much lower ionic conductivities and higher costs of organic liquid electrolytes possibly impose additional constrains on large-scale application of nonaqueous sodium-ion batteries.T oo vercome the drawbacks of organic liquid electrolytes,t he development of sodium-ion batteries with aqueous electrolytes may represent apromising approach for large-scale storage of electrical energy. [16][17][18][19] Recently,anumber of transition metal oxides,P russian blue analogues,a nd polyanionic frameworks have demonstrated stable sodium storage performance in aqueous electrolytes. [20][21][22][23][24] Particular interests have also been focused on sodium storage in NASICON (Na Super Ionic Conductors)-type compounds because of their structural stability, their large ionic channels,a nd the abundance of sodiuminsertion sites.…”

mentioning

confidence: 99%

An Aqueous Symmetric Sodium‐Ion Battery with NASICON‐Structured Na₃MnTi(PO₄)₃

Gao

Goodenough

2016

Angewandte Chemie

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As ymmetric sodium-ion battery with an aqueous electrolyte is demonstrated;i tu tilizes the NASICON-structured Na 3 MnTi(PO 4 ) 3 as both the anode and the cathode.The NASICON-structured Na 3 MnTi(PO 4 ) 3 possesses two electrochemically active transition metals with the redoxc ouples of Ti 4+ /Ti 3+ and Mn 3+ /Mn 2+ working on the anode and cathode sides,r espectively.T he symmetric cell based on this bipolar electrode material exhibits aw ell-defined voltage plateau centered at about 1.4 Vi na na queous electrolyte with as table cycle performance and superior rate capability.T he advent of aqueous symmetric sodium-ion battery with high safety and low cost may provide as olution for large-scale stationary energy storage.

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“…Researchers have recently demonstrated new types of Zn anode based rechargeable batteries, namely zinc ion batteries (ZIBs) and zinc ion based hybrid batteries that featuring high reversibility. [192][193][194][195] This section will mainly focus on these two types of rechargeable batteries.…”

Section: Zinc Based Anode Materialsmentioning

confidence: 99%

“…One uses Li + or Na + intercalation/ de-intercalation materials as cathode (e.g., LiMn 2 O 4 , [198][199][200] Na 0.95 MnO 2 , [201] Na 3 V 2 (PO 4 ) 3 /C), [194] . [198] This battery system showed excellent cycling stability with ≈90% capacity retention after 1000 cycles for un-doped LiMn 2 O 4 and ≈95% capacity retention after 4000 cycles for cation doped LiMn 2 O 4 .…”

Section: Zinc Based Anode Materialsmentioning

confidence: 99%

“…[194] Another type of Zn 2+ based hybrid batteries is based on anions hosting organic materials as the cathode materials, such as polyaniline (PANI), [192,202,203] poly (3,4-ethylenedioythiophene) (PEDOT), [204] and poly(5-cyanoindole) [205] as the cathode material. The reversible redox characters of the conducting polymer are utilized to host anions to complete the battery reactions.…”

Section: Zinc Based Anode Materialsmentioning

confidence: 99%

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Low‐Cost Metallic Anode Materials for High Performance Rechargeable Batteries

Wang

Zhang

Lee

et al. 2017

Advanced Energy Materials

194

107

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density. Therefore, developing highcapacity anode and cathode materials or new battery systems have drawn extensive attentions. [6,[21][22][23][24][25][26][27][28] Metal anodes, especially those with high-capacity and low-cost are promising alternative anode materials for LIBs in replace of graphite anode. [29][30][31][32][33][34] Generally, the metal anodes electrochemically alloy/ de-alloy with Li + to complete the battery reaction, which can store more energy than the intercalation/deintercalation mechanism in graphite. Table 1 displays the electrochemical properties of typical metallic anodes (Al, Sn, Zn, Mg, Sb, and Bi) with Li and graphite for comparison. While the graphite anodes suffer from low capacity (372 mA h g −1 ) and Li anodes suffer from severe safety issues caused by lithium dendrites, these metal anodes have many advantages in terms of high theoretical capacities, moderate operation potential for less dendrites formation, high abundance and low cost. [35] For example, aluminum has high theoretical capacity (993 mA h g −1 or 1411 mA h cm −3 for LiAl) with moderate potential plateau (≈0.38 V vs Li + /Li). [35,36] Considering both of the capacity increase and voltage drop by using metal anodes in a LIB model, Obrovac et al. calculated the volumetric energy increase in comparison to graphite based commercial battery (Table 1). [37] In such a model, the volumetric energy densities could be increased by different extents ranging from 10-42% when metal anodes were used. It is worth noticing that some recent studies have raised the idea of directly using metal foil as active anode material and simultaneously current collector. [38,39] This strategy can eliminate the usage of binder and conductive carbon black for anode preparation, simplify the battery processing steps, and also increase the loading amount of active materials, thus further enhancing the energy density and reducing the battery prices.While the metal anodes show good potential for application in high-performance LIBs, the main challenge for these metallic anodes is their large volume change caused by lithiation/delithiation process during cycling. [37,40,41] As the lithiation proceeds more deeply, the volume change becomes more severely for alloying anodes. For instance, the volume change of Sn (260%, Li 4.4 Sn) is larger than Al (97%, LiAl). The huge volume change could cause crack and pulverization of metal anodes, resulting in quick capacity decay and short cycling life. [42][43][44][45][46] Besides, metallic anode materials usually exhibited high first-cycle capacity loss due to their high reactivity withThe ever-growing market of portable electronic devices and electric vehicles has significantly stimulated research interests on new-generation rechargeable battery systems with high energy density, satisfying safety and low cost. With unique potentials to achieve high energy density and low cost, rechargeable batteries based on metal anodes are capable of storing more energy via an alloying/de-alloying process, in comparison to tradi...

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Hybrid aqueous battery based on Na3V2(PO4)3/C cathode and zinc anode for potential large-scale energy storage

Cited by 159 publications

References 49 publications

Highly Sustainable Zinc Anodes for a Rechargeable Hybrid Aqueous Battery

Highly Sustainable Zinc Anodes for a Rechargeable Hybrid Aqueous Battery

An Aqueous Symmetric Sodium‐Ion Battery with NASICON‐Structured Na₃MnTi(PO₄)₃

Low‐Cost Metallic Anode Materials for High Performance Rechargeable Batteries

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Hybrid aqueous battery based on Na3V2(PO4)3/C cathode and zinc anode for potential large-scale energy storage

Cited by 159 publications

References 49 publications

Highly Sustainable Zinc Anodes for a Rechargeable Hybrid Aqueous Battery

Highly Sustainable Zinc Anodes for a Rechargeable Hybrid Aqueous Battery

An Aqueous Symmetric Sodium‐Ion Battery with NASICON‐Structured Na3MnTi(PO4)3

Low‐Cost Metallic Anode Materials for High Performance Rechargeable Batteries

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An Aqueous Symmetric Sodium‐Ion Battery with NASICON‐Structured Na₃MnTi(PO₄)₃