Thermogravimetric analysis (TG) is one of the most common instrumental techniques used for the characterization of pastes, mortars and concretes based on both calcium hydroxide or Portland cement.Important information about pozzolanic materials can be assessed concerning to calcium hydroxide consumption and the formation of new hydrated products. Nevertheless, in some cases, problems associated to the overlapped decomposition processes for hydrates difficult the analysis of obtained data.In this paper the use of high resolution thermogravimetric analysis (HRTG), a powerful technique that allows separating decomposition processes in analysis of hydrated binders, was performed for spent FCC catalyst -Portland cement pastes. These pastes were monitored for 1, 4, 8 hours and 1, 2, 3, 7 and 28 curing days. In order to study the influence of the pozzolanic material (spent FCC catalyst), Portland cement replacements of 5, 15 and 30 % by mass were carried out. The presence of spent FCC catalyst in blended pastes modified the amount and the nature of the formed hydrates, mainly ettringite and stratlingite.