2008
DOI: 10.1016/j.msec.2007.10.022
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Hydrogen and nitrogen effects on optical and structural properties of amorphous carbon

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Cited by 21 publications
(4 citation statements)
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“…As far as magnetic storage field is concerned, higher storage densities require the read/write head to approach closer to the magnetic layer, so it is expected to develop even thinner ta-C films of 1-2 nm thickness and still with excellent tribological protection and corrosion resistance [6]. The incorporation of certain chemical elements into ta-C films including nitrogen has been found to improve effectively their structures and properties [7][8][9][10][11], such as internal thermal stress and thermal stability, optical absorption, electronic conductivity and mechanical hardness, thus greatly necessitate and broaden their application fields.…”
Section: Introductionmentioning
confidence: 99%
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“…As far as magnetic storage field is concerned, higher storage densities require the read/write head to approach closer to the magnetic layer, so it is expected to develop even thinner ta-C films of 1-2 nm thickness and still with excellent tribological protection and corrosion resistance [6]. The incorporation of certain chemical elements into ta-C films including nitrogen has been found to improve effectively their structures and properties [7][8][9][10][11], such as internal thermal stress and thermal stability, optical absorption, electronic conductivity and mechanical hardness, thus greatly necessitate and broaden their application fields.…”
Section: Introductionmentioning
confidence: 99%
“…However, it has been mainly reported by some research groups for the nitrogen incorporation into ultra-thin ta-C films during direct FCVA deposition process [4,10,13], and the incorporation behavior has remained inefficient because the appealing diversity of the bonding configurations allows nitrogen to be incorporated in many conditions [8,14].…”
Section: Introductionmentioning
confidence: 99%
“…Thus, since the localized electrons play an important role in determining the optical properties of a-C, due to the reduced spatial overlapping of and states wave overlapping, the contribution of -Ã and -Ã can be neglected. 21,22) The optical band gap of our a-C thin film was deduced using the Tauc plot 23) as shown in Fig. 8 in the absorption region ( $ 10 3 -10 4 cm À1 ).…”
Section: Resultsmentioning
confidence: 99%
“…On the other hand, a-C contains high concentration of dangling bonds, which will affect the band gap value. Thus, since the localized π electrons play an important role in determining the optical properties of a-C, due to the reduced spatial overlapping of π and σ states wave overlapping, the contribution of σ-π* and π-σ* can be neglected [23,24].…”
mentioning
confidence: 99%