“…To calculate the Gen j term at each x i and t k , the reaction coordinate method was implemented to simultaneously solve for the nonstoichiometry of CeO 2− δ and equilibrium of the reactions of interest. 32 The considered reactions and their corresponding equilibrium constant expressions ( K eq ) in terms of the partial pressure of each gas species ( p j ) are summarized in Table 2. K eq for the first three reactions are only a function of temperature and are indexed from NIST-JANAF thermochemical tables.…”
A cycling strategy is presented for simultaneous improvement of conversion and syngas selectivity during chemical looping reforming. Periodic recharging is used to re-establish a favorable nonstoichiometry profile during non-steady cycling.
“…To calculate the Gen j term at each x i and t k , the reaction coordinate method was implemented to simultaneously solve for the nonstoichiometry of CeO 2− δ and equilibrium of the reactions of interest. 32 The considered reactions and their corresponding equilibrium constant expressions ( K eq ) in terms of the partial pressure of each gas species ( p j ) are summarized in Table 2. K eq for the first three reactions are only a function of temperature and are indexed from NIST-JANAF thermochemical tables.…”
A cycling strategy is presented for simultaneous improvement of conversion and syngas selectivity during chemical looping reforming. Periodic recharging is used to re-establish a favorable nonstoichiometry profile during non-steady cycling.
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