“…Non‐linear, hysteretic storage–discharge mechanisms are associated with time lags in the transfer of mass or information through a watershed, suggesting that the volume and physical attributes (e.g., saturated vs. unsaturated) of decoupled storage affect catchment transport timescales, hydraulic response to external fluxes, and the sensitivity of evapotranspiration to climate variations (e.g., Nippgen, McGlynn, Emanuel, & Vose, ; Riegger & Tourian, ; Tani, ; Torres et al, ). Conceptual hydrologic models often feature decoupled storage elements (Birkel, Soulsby, & Tetzlaff, ; Botter, Porporato, Rodriguez‐Itubre, & Rinaldo, ; Lehmann, Hinz, McGrath, Tromp van Meerveld, & McDonnell, ), whose process representations are strong determinants of catchment discharge response and the emergent, hysteretic features of modelled storage–discharge relationships (Fovet, Ruiz, Hrachowitz, Faucheux, & Gascuel‐Odoux, ). Thus, estimating the volumes and temporal dynamics of hydraulically decoupled catchment storage could provide important new insights into catchment processes and improve hydrological modelling frameworks.…”