Hydrothermal synthesis and optical property of ZnS/CdS composites

Abstract

ZnS/CdS semiconductor composites were synthesized successfully by combining a hydrothermal route with a homogeneous precipitation process. The as-prepared products were characterized by x-ray diffraction, scanning electron microscopy, and energy dispersive x-ray spectrometer. The results showed that the as-prepared products were composed of ZnS microspheres with a facecentered cubic phase and CdS nanoparticles with hexagonal phase, CdS nanoparticles were found to be assembled on the surfaces of the cubic ZnS microspheres. In addition, the ultraviolet-visible absorption spectroscopy and the room temperature photoluminescence (PL) spectroscopy of the ZnS microspheres and ZnS/CdS composites were also investigated. The PL testing indicated that the emission peak of as-prepared ZnS/CdS composites not only exhibited an obvious blue shift but also its intensity had a large enhancement compared to the pure ZnS microspheres. Furthermore, the photocatalytic degradation test showed that the as-prepared ZnS/CdS composites showed excellent photocatalytic degradation activity for methyl orange under UV irradiation. This enhanced activity may be related to the modification of CdS nanoparticles on the surfaces of ZnS microspheres.

Reduced graphene oxide wrapped ZnS–Ag2S ternary composites synthesized via hydrothermal method: Applications in photocatalyst degradation of organic pollutants

“…Zhang et al noticed the improved degradation rate of a ZnS-Ag 2 S composite relative to that of bare ZnS [21]. Similarly, novel ZnS composites such as TiO 2 /ZnS [22], ZnS/CdS [23], ZnS/ZnO [24], ZnS-CuS [25], and ZnS-CoFe 2 O 4 [26] have been synthesized for prominent applications. Among these, ZnS-Ag 2 S is a well-known heterostructure for its characteristic structural, optical and photoluminescence (PL) properties [27][28][29].…”