Hydrothermal synthesis, characterization and crystal structures of two new layered lead(ii) diphosphonates

Synthesis, Crystal Structures and Photoluminescent Properties of Three Novel Cadmium(II) Compounds Constructed from 5‐Sulfoisophthalic Acid (H3SIP)

“…[21,22] The inorganic oxide layer contains two types of chair-like [Cd 4 (µ 3 -OH) 2 There are several compounds containing a chair-shaped tetranuclear cadmium cluster, [23][24][25] but those with two capping µ 3 -OH groups are rare. It is even more interesting that the [Cd 4 (µ 3 -OH) 2 ] cluster units are interconnected by the Cd(3)(µ 2 -OH) 2 (CO 2 ) unit into an unusual inorganic oxide layer.…”

Hydrothermal syntheses, characterizations and crystal structures of two new lead(II) diphosphonates with a layered and a microporous structure

“…A number of lead(II) carboxylate-phosphonates and lead(II) aminodiphosphonates with layered or 3D network structures have been reported [5][6][7][8][9][10][11][12]. In order to understand the effect of the substituents attached on the structures of metal aminodiphosphonates formed, we have studied a number of divalent metal compounds with RN(CH 2 PO 3 H 2 ) 2 (R ¼ Me, C 6 H 5 -CH 2 -) [13,14]. As an expansion of our study, we have synthesized a new aminodiphosphonic acid attached with an large alkyl group, N -isobutylimino-bis(methylene-phosphonic acid), Me 2 CHCH 2 N(CH 2 PO 3 H 2 ) 2 (H 4 L).…”

Synthesis, crystal structures and luminescence properties of lanthanide oxalatophosphonates with a three-dimensional framework structure

“…Table S2: Selected bond angles (1) for compounds 1-6. CCDC reference numbers 670477-670481 (1-5) and 686602 (6). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b814400a…”

“…[1][2][3][4][5] Usually, the metal phosphonates adopt layered or pillared layered structures, with the organic groups filling in between the inorganic layers. [6][7][8][9][10] Other structural types have also been observed in some phosphonates, among which the openframework and porous structures are of particular interest. [11][12][13][14][15][16] The strategy of attaching functional groups such as amine, hydroxyl and carboxylate groups to the phosphonic acid has proven to be effective for the isolation of a variety of metal phosphonates with open-framework and microporosity.…”