Hydrothermal synthesis, structure and properties of a new 3D two-fold Co-based coordination framework

Chen, Man-Sheng; Li, Xiaojie; Deng, Yi-Fang; Zhang, Chunhua; Sheng, Liang-Bing; Lu, Weihong

doi:10.1080/24701556.2020.1852255

Cited by 1 publication

(1 citation statement)

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“…With the acceleration of industrialization, more and more toxic dye contaminants, which are hard to be biodegraded e ectively, are discharged into the water system without any pretreatment, leading to sewer pollution that will cause lots of fatal diseases to human beings and other living things [7]. Recently, semiconductive MOFs, which not only feature a large surface area, high porosity, tunable pore structure, and coordinated unsaturated metal site but also can harvest solar energy e ectively, have been successfully synthesized, and further utilized as photocatalysts in order to e ectively degrade the abovementioned dyes into harmless small molecules under the irradiation of ultraviolet or visible light [8][9][10][11][12].…”

Section: Introductionmentioning

confidence: 99%

Construction of a New 3D Cu(II) Compound with Photocatalytic Activity and Therapeutic Effect on Ventriculitis

Chen

Mao

2022

Journal of Chemistry

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A new Cu(II) compound, that is {[Cu(L)(ClO4)(H2O)(CH3CN)](ClO4)}n (1, L is 4-(furan-2-yl)-2,6-bis(pyridin-2-yl)pyridine), was solvothermally synthesized and structurally characterized. It features a 0D isolated unit, and these 0D isolated units are further hydrogen-bonded into a 3D supramolecular framework. The framework of 1 can be stable up to 284°C, and the optical band gap of 1 is 3.71 eV. Under the irradiation of ultraviolet light, complex 1 as a photocatalyst exhibits high activity for methylene blue (MB) degradation in the water solution. The above compound’s inhibitory activity on the inflammatory cytokines releasing was tested through exploiting ELISA detection. The real time RT-PCR was conducted to assess the compound’s suppression on the expression of bacterial survival gene.

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