tert-Butyl Hydroperoxide

Non-covalent interactions of the hydroperoxo group in crystalline adducts of organic hydroperoxides and their potassium salts

“…Organic hydroperoxides are an important class of compounds that can be used to oxidize a wide range of substrates with high selectivity. 1–4 These compounds are used in peroxidation reactions to synthesize more complex organic peroxides. 5–7 As radical initiators, organic hydroperoxides open pathways for obtaining products of free-radical reactions, including industrially important polymeric materials.…”

Zinc Difluoromethanesulfinate

“…It is important to note that TBHP must be added slowly and the reaction temperature should be kept at 0 • C until completion of the addition of TBHP on medium-to large-scale reactions (see TBHP 4 ).…”

Zinc Isopropylsulfinate

“…Handling, Storage, and Precautions: zinc isopropylsulfinate is stable to ambient-temperature storage under air and no particular precautions need to be taken when handling this compound. When performing the requisite reaction, however, TBHP is used as the oxidant to form the reactive species in solution, and TBHP requires some caution when handling (see TBHP 4 ).…”