Land surface temperature (LST) is a phenomenon that significantly affects the environment, the cities' liveability, and the citizens' well-being. This Study aims to perform a comparative study of the microclimate and Surface Urban Heat Island (SUHI) phenomenon of two metropolitan cities of India, i.e. Jaipur and Ahmedabad, using MODIS Satellite data, whereas Landsat Data was used to analyse the Land Surface Characteristics by an index-based approach. The Study's findings reveal that Ahmedabad has 35.53 per cent of the total area classified as having a low potential, and 13.55 per cent is designated as a high potential LST zone. Meanwhile, in Jaipur, 30.45 per cent of the city's total area is identified as a low potential LST zone and 12.69 per cent as a high potential LST zone. This Study highlights the importance of mitigating the UHI phenomenon in urban centres for the overall well-being of city dwellers. It will help policymakers and stakeholders comprehend plans and take initiatives to minimise the effects of the UHI phenomenon on rapidly growing cities.