Improved cotton fabrics properties using zinc oxide-based nanomaterials: A review

Mohammadipour-Nodoushan, Roya; Shekarriz, Shahla; Shariatinia, Zahra; Heydari, Abolfazl; Montazer, Majid

doi:10.1016/j.ijbiomac.2023.124916

Cited by 25 publications

(4 citation statements)

References 222 publications

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“…28−30 Zinc oxide also stands out for it is low toxicity and cost-effectiveness, making it feasible for the large-scale production of UV-protective textiles. 31,32 Therefore, to enhance the UV-protective ability of polyphenols, zinc was introduced into the medium to yield ZP NPs. When polyphenols were introduced into the zinc solution, the polyphenols served as reducing agents, leading to the formation of ZP NPs by forming complexes with hydroxyl and keto groups in polyphenols.…”

Section: ■ Results and Discussionmentioning

confidence: 99%

“…As summarized in Table S1, 6 natural polyphenols (quercetin-3-glucuronide, myricetin-3-galactoside, gossypin, phlorizin, kaempferol, and myricetin-3-arabinoside) were utilized in the synthesis of ZP NPs. Zinc was already known for its high UV absorption and reflection ability due to its wide semiconductor band gap, which ensures robust protection against UV-induced damages and sunburn on skin. − Zinc oxide also stands out for it is low toxicity and cost-effectiveness, making it feasible for the large-scale production of UV-protective textiles. , Therefore, to enhance the UV-protective ability of polyphenols, zinc was introduced into the medium to yield ZP NPs. When polyphenols were introduced into the zinc solution, the polyphenols served as reducing agents, leading to the formation of ZP NPs by forming complexes with hydroxyl and keto groups in polyphenols.…”

Section: Resultsmentioning

confidence: 99%

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Green Nanoengineered Fabrics: Waste-Derived Polyphenol-Zinc@ Silica Core–Shell Reactive Janus Nanoparticles for Functional Fabrics

Meganathan,

Ramalingam

2024

ACS Appl. Mater. Interfaces

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Fabricating Janus nanoparticle−functionalized fabrics with UV protection, strength enhancement, self-cleaning properties, and wash durability, with a biocompatible nature, is crucial in modern functional fabrics engineering. Particularly, tailoring multifunctional nanoparticles capable of exhibiting several distinct properties, utilizing low-cost raw materials, and adhering to green chemistry principles is pivotal. A fabrication strategy for developing multifunctional reactive Janus nanoparticles, utilizing waste-derived natural polyphenol (quercetin-3-glucuronide, myricetin-3galactoside, gossypin, phlorizin, kaempferol, myricetin-3-arabinoside)−integrated zinc-silica core−shell Janus nanoparticles with UV protection, strength enhancement, and self-cleaning properties, is proposed. Polyphenols were utilized as sustainable precursors for synthesizing zinc-polyphenol complexes, which were then encapsulated within a silica shell to form a core−shell structure. Furthermore, Janus particles were created by introducing a bifunctional layer with half amine/carboxylic acid and half methyl terminals, imparting reactive hydrophilic and hydrophobic properties. Janus-coated textiles and leather exhibited significant attenuation of harmful UV radiation, with water contact angle measurements confirming improved water repellency. The coexistence of natural phenols and bifunctional groups within a material bolstered textile strength, fostering superior adhesion and markedly enhancing wash durability. This eco-friendly approach, utilizing waste-derived materials, presents a promising solution for sustainable textile engineering with enhanced performance in UV protection and water resistance, thereby contributing to the advancement of green nanotechnology in textile applications.

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Section: ■ Results and Discussionmentioning

confidence: 99%

Section: Resultsmentioning

confidence: 99%

Green Nanoengineered Fabrics: Waste-Derived Polyphenol-Zinc@ Silica Core–Shell Reactive Janus Nanoparticles for Functional Fabrics

Meganathan,

Ramalingam

2024

ACS Appl. Mater. Interfaces

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“…These TiO 2 forms exhibited favorable adsorption properties, capable of adsorbing gases like CO and CO 2 , as well as some small molecules resulting from the decomposition of combustibles under heat. By reducing the release of harmful gases and facilitating proximity with small molecules, TiO 2 contributed to catalyzing these molecules alongside silver nanoclusters on the surface of e-MXene into solid substances [44,45]. The test results of TG-IR and cone calorimetry confirmed that the carbon-forming effect of the EVA/e-MXene@Ag1.0 composite was enhanced by the excellent dispersion of e-MXene@Ag1.0, the adsorption of TiO 2 , and the synergistic catalysis with silver nanoclusters.…”

Section: Flame Retardant Mechanism Elucidation Of Eva Compositesmentioning

confidence: 99%

In situ growth of Ag nanoparticles on the surface of MXene by γ-ray irradiation to fabricate EVA composite: the improvement of flame retardancy, smoke suppression, and mechanical properties

Xu,

Li,

Wang

et al. 2024

J. Phys. D: Appl. Phys.

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A large amount of toxic smoke and heat generated by the combustion of ethylene vinyl acetate copolymer (EVA) poses a significant threat to human fire escape evacuation. This work aims to use γ-ray to prepare e-MXene@Ag hybrid flame-retardant materials by the method of in-situ reduction, and EVA composites are prepared by melt blending to reduce the smoke and toxic gases produced during combustion significantly. Compared with pure EVA, the total heat release, total smoke release, and the production rate of CO and CO2 produced by the combustion of EVA composite with 1wt% e-MXene@Ag1.0 decreased by 30.3%, 33.3%, 18.2%, and 20.1% respectively, while the content of residue increased by 907.4%. The fire hazard reduction of EVA composite materials was due to the physical barrier, catalytic carbonization and adsorption of the e-MXene@Ag1.0 hybrid. In addition, e-MXene@Ag1.0 can also further increase the mechanical properties of EVA composites due to its own "multi-contact point limit structure."

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“…On the contrary, cotton cloth (CC), with its abundance of surface hydroxyl ions, coupled with its low mass density, flexibility, and biodegradability, presents itself as a promising substrate for the hierarchical growth of electroactive materials when compared to other existing flexible counterparts. 4,5 Electrode materials frequently employed in flexible supercapacitors, such as metal oxides, conductive polymers (polypyrrole and polyaniline), metal hydroxides, etc. suffer from the limitations of cycling stability, fragility, and restricted voltage windows.…”

Section: Introductionmentioning

confidence: 99%

Poly(N-vinylpyrrolidone)-Assisted Crystal Growth of Zeolitic Imidazolate Framework (ZIF-67) and Electrochemical Properties of Its Derivatives for Flexible Supercapacitors

Jain,

Joshi,

Poddar

2024

Crystal Growth & Design

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A simple and explicit wet chemical method enables the roomtemperature crystallization of the zeolitic imidazolate framework (ZIF-67) using cotton-cloth (CC) as a substrate; where time-dependent Avrami's kinetic studies demonstrated sluggish nucleation and fast crystal growth resulting in unprecedented morphologies−truncated cubes [synthesized without poly(Nvinylpyrrolidone); PVP], and rhombic dodecahedra (with PVP) with average sizes ranging from 500 nm to 1.41 μm; wherein amphiphilic PVP plays a crucial function of structure directing agent by modulation of complex formation and deprotonation equilibria. To study the potential of pristine ZIF-67 (ZP0) and PVP-functionalized ZIF-67 (ZP50, ZP100, and ZP200) grown on the CC substrate for application as a flexible electrode in supercapacitors, ZP0, ZP50, ZP100, and ZP200 were annealed to form CZP0, CZP50, and CZP100, respectively. Areal capacitances of 181 and 214 mF•cm −2 were achieved at a current density of 1 mA•cm −2 and a potential window of 1.6 V for CZP0 and CZP100, respectively, and compared to the derivatives without PVP; CZP100 exhibited a superior energy density of 76.3 μWh•cm −2 and a capacitance retention of 84.3% after 5000 cycles at a current density of 0.5 mA•cm −2 .

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Improved cotton fabrics properties using zinc oxide-based nanomaterials: A review

Cited by 25 publications

References 222 publications

Green Nanoengineered Fabrics: Waste-Derived Polyphenol-Zinc@ Silica Core–Shell Reactive Janus Nanoparticles for Functional Fabrics

Green Nanoengineered Fabrics: Waste-Derived Polyphenol-Zinc@ Silica Core–Shell Reactive Janus Nanoparticles for Functional Fabrics

In situ growth of Ag nanoparticles on the surface of MXene by γ-ray irradiation to fabricate EVA composite: the improvement of flame retardancy, smoke suppression, and mechanical properties

Poly(N-vinylpyrrolidone)-Assisted Crystal Growth of Zeolitic Imidazolate Framework (ZIF-67) and Electrochemical Properties of Its Derivatives for Flexible Supercapacitors

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