Improved OER performance of an Anderson-supported cobalt coordination polymer by assembling with acetylene black

Abstract

Anderson-Evans type polyoxometalates (POMs) are regarded as excellent nanosized inorganic building blocks for the construction of multifunctional hybrid materials because of their ease of covalent modification. A novel Anderson-based coordination...

Latest progress in asymmetrically functionalized Anderson-type polyoxometalates

“…Anderson-type POMs are one of the most important groups of the POM family. 18–20 They play an important role in electrocatalytic oxygen evolution, 21 oxidative desulfurization, 22,23 dye degradation, 24 antibacterial activity 9 and other application areas. 25 The structure of Anderson POMs was proposed by J. S. Anderson in 1937, and then confirmed by H. T. Evans using X-ray.…”

An organic–inorganic hybrid polyoxoniobate decorated by a Co(iii)-amine complex for electrocatalytic urea splitting

“…18 As a result, creating a structurally stable precursor at the molecular level using the grafting method to efficiently disperse catalytically active sites has become a significant challenge for electrocatalysis. 19 Based on this design concept, it is believed that crystalline catalysts with clear structures could provide an opportunity where this concept is put into practice and extend the possibilities of efficient hydrogen production.…”

Ligand leaching enabling improved electrocatalytic oxygen evolution performance

“…[11][12][13][14] Some redox-active coordination polymers have been reported as efficient electrocatalysts for the OER recently. [15][16][17] The chemical stability of MOFs is the key issue for their application as catalysts. 18,19 In a greater number of cases, MOFs act as pre-catalysts.…”

“…11–14 Some redox-active coordination polymers have been reported as efficient electrocatalysts for the OER recently. 15–17…”