In situ rapid versatile method for the preparation of zirconium metal-organic framework filters

Metal–organic frameworks on versatile substrates

“…Textile bers are exible, breathable, and affordable and have been widely recognized as one of the advantageous supports for MOF fabrication. Textile bers, including cotton fabric, [277][278][279][280][281][282][283][284][285][286][287][288] paper, [289][290][291][292][293] biomass materials such as wood, [294][295][296][297] and textile cellulose, [298][299][300][301][302][303][304][305][306][307][308][309] are widely reported. For instance, Manos et al obtained cotton fabric, which was pre-functionalized with PDA, providing catechol units for the strong bonding of MIL-53 on a cotton surface.…”

Aluminum Molecular Ring Meets Deep Eutectic Solvents: Adaptive Assembly and Optical Behavior

“…Deep eutectic solvents (DESs) involving both hydrogen bond donors (HBDs) and acceptors (HBAs) are considered emerging green solvents related to ionic liquids (ILs). , Although they have been used in the isolation of crystalline materials such as molecular sieves, metal–organic frameworks, and cluster materials, − they have not been reported for the synthesis of metal molecular rings. In the DES melting system, the size of the halogen ion in the quaternary ammonium salt HBA matches the center of the Al-oxo molecular ring, while organic cations can combine with π-conjugated ligands through supramolecular interaction.…”