2006
DOI: 10.1002/chin.200609020
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In situ X‐Ray Diffraction Analysis of the Pd—H System at High Pressure

Abstract: Equilibria E 4000In situ X-Ray Diffraction Analysis of the Pd-H System at High Pressure -[5GPa, 20-800°C]. -(AZAMBUJA*, V.; MIRAGLIA, S.; FRUCHART, D.; TAVARES, S.; DOS SANTOS, D.; MEZOUAR, M.; J. Alloys Compd. 404-406 (2005) 1-2, 77-81; Lab. Cristallogr., CNRS, Univ. Joseph Fourier, F-38042 Grenoble, Fr.; Eng.) -Schramke 09-020

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“…3,4 Work on substoichometric PdH x , and PdD x (x ≤ 1) has been carried out in the search for still higher T c . 5,6 For these compositions, PdH x and PdD x exhibit an inverse isotope effect, in which, contrary to the established formalism for Bardeen-Cooper-Schrieffer (BCS)-type superconductivity, PdD x has a higher superconducting transition temperature than PdH x . 7 The inverse isotope effect has been attributed to anharmonicity in the lattice vibrations as supported by measured Debye−Waller factors and theoretical calculations.…”
Section: Introductionmentioning
confidence: 86%
“…3,4 Work on substoichometric PdH x , and PdD x (x ≤ 1) has been carried out in the search for still higher T c . 5,6 For these compositions, PdH x and PdD x exhibit an inverse isotope effect, in which, contrary to the established formalism for Bardeen-Cooper-Schrieffer (BCS)-type superconductivity, PdD x has a higher superconducting transition temperature than PdH x . 7 The inverse isotope effect has been attributed to anharmonicity in the lattice vibrations as supported by measured Debye−Waller factors and theoretical calculations.…”
Section: Introductionmentioning
confidence: 86%