2023
DOI: 10.1021/acsaem.2c04132
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Incorporating Microporous Zn3 and Zn2Cd MOFs into Pebax/PVDF Mixed Matrix Membranes for Improved Carbon Dioxide Separation Performance

Abstract: A pair of related metal–organic frameworks (Zn 3 and Zn 2 Cd) developed in our group were incorporated into Pebax 30R51 and PVDF Kynar 761 polymers to fabricate mixed matrix membranes (MMMs). These MOFs were chosen due to the carbon dioxide molecular sieving ability of Zn 3 , and the slightly larger pore aperture of Zn 2 Cd that allows carbon dioxide and larger gases to enter the pores. For Pebax-based MMMs, this work demonstrated an over two-fold and four-and-a-half-fold increase in carbon dioxide perm… Show more

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“…With our ongoing interests in developing MOFs for environmental applications such as storage, 24 separation, 25,26 and reactivity of gases, 27 the present work focuses on sensing ammonia gas. As illustrated in Fig.…”
Section: Introductionmentioning
confidence: 99%
“…With our ongoing interests in developing MOFs for environmental applications such as storage, 24 separation, 25,26 and reactivity of gases, 27 the present work focuses on sensing ammonia gas. As illustrated in Fig.…”
Section: Introductionmentioning
confidence: 99%