In order to study the evolution of nanoparticles during aluminum wire electrical explosion, a nanoparticle formation model considering layered motion was developed, and an experimental system was set up to carry out electrical explosion experiments of 0.1 mm and 0.2 mm Al wires. The characteristic parameters and evolution process during the formation of nanoparticles were calculated and analyzed. The results show that the maximum velocities of the innermost and outermost layers are about 1200 m·s-1 and 1600 m·s-1, and the velocity of the middle layer is about 1400 m·s-1, respectively. Most of the nanoparticles are formed in the temperature range of 2600 ~ 2500 K. The characteristic temperature for the formation of aluminum nanoparticles is ~ 2520 K, which is also the characteristic temperature of other parameters. The formed nanoparticles diameter distribution ranging from 18 nm to 110 nm, and most of them are distributed near 22 nm.The variation of saturated vapor pressure determines the temperature distribution range of particle nucleation. There is a minimum critical diameter of particles (~ 25 nm), particles smaller than the critical diameter can grow into larger particles during surface growth. Particle motion has an effect on the surface growth and aggregation process of particles, and also on the distribution area of larger diameter particles. The simulation results are in good agreement with the experiments. It provides a method to estimate the size and distribution of nanoparticles, which is of great significance to understand the formation process of particles during the evolution of wire electrical explosion.