2017
DOI: 10.1002/chem.201702831
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Inside Back Cover: Noninnocent β‐Diiminate Ligands: Redox Activity of a Bis(alkylimidazole)methane Ligand in Cobalt and Zinc Complexes (Chem. Eur. J. 45/2017)

Abstract: The first example of a redox non‐innocent β‐diketiminate‐type ligand, bis(1‐methyl‐4,5‐diphenyl‐1H‐imidazol‐2‐yl)methane anion, BMIMPh2−, is presented. In homoleptic metal complexes, these ligands are susceptible toward oxidation, covering three different oxidation states. The redox behavior of complexes featuring BMIMPh2− or related ligands are expected be a versatile tool in contemporary research within the context of chemical catalysis or activation of small molecules. More information can be found in the C… Show more

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